Carbon Disulfide Cosolvent Electrolytes for High-Performance Lithium Sulfur Batteries
文献类型：期刊论文
| 作者 | Gu, Sui1,2,3; Wen, Zhaoyin1; Qian, Rong2; Jin, Jun1; Wang, Qingsong1,3; Wu, Meifen1; Zhuo, Shangjun2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2016-12-21 |
| 卷号 | 8期号:50页码:34379-34386 |
| 关键词 | carbon disulfide electrolyte additive SEI lithium sulfur battery |
| 英文摘要 | Development of lithium sulfur (Li-S) batteries with high Coulombic efficiency and long cycle stability remains challenging due to the dissolution and shuttle of polysulfides in electrolyte. Here, a novel additive, carbon disulfide (CS2), to the organic electrolyte is reported to improve the cycling performance of Li-S batteries. The cells with the CS2-additive electrolyte exhibit high Coulombic efficiency and long cycle stability, showing average Coulombic efficiency >99% and a capacity retention of 88% over the entire 300 cycles. The function of the CS2 additive is 2-fold: (1) it inhibits the migration of long-chain polysulfides to the anode by forming complexes with polysulfides and (2) it passivates electrode surfaces by inducing the protective coatings on both the anode and the cathode. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Science & Technology - Other Topics ; Materials Science |
| 关键词[WOS] | LI-S BATTERIES ; SOLID-ELECTROLYTE ; COMPOSITE ; CATHODE ; ION ; XPS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000390728900025 |
| 源URL | [http://ir.sic.ac.cn/handle/331005/21914]  |
| 专题 | 上海硅酸盐研究所_能量转换材料重点实验室_期刊论文 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Ceram, Natl Ctr Inorgan Mass Spectrometry Shanghai, Shanghai 200050, Peoples R China 3.Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai 200050, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gu, Sui,Wen, Zhaoyin,Qian, Rong,et al. Carbon Disulfide Cosolvent Electrolytes for High-Performance Lithium Sulfur Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(50):34379-34386. |
| APA | Gu, Sui.,Wen, Zhaoyin.,Qian, Rong.,Jin, Jun.,Wang, Qingsong.,...&Zhuo, Shangjun.(2016).Carbon Disulfide Cosolvent Electrolytes for High-Performance Lithium Sulfur Batteries.ACS APPLIED MATERIALS & INTERFACES,8(50),34379-34386. |
| MLA | Gu, Sui,et al."Carbon Disulfide Cosolvent Electrolytes for High-Performance Lithium Sulfur Batteries".ACS APPLIED MATERIALS & INTERFACES 8.50(2016):34379-34386. |
入库方式： OAI收割
来源：上海硅酸盐研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。