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Two-dimensional MXene Ti3C2 produced by exfoliation of Ti3AlC2

文献类型:期刊论文

作者Feng, Aihu1,2; Yu, Yun1; Wang, Yong1,2; Jiang, Feng1,2; Yu, Yang1; Mi, Le1; Song, Lixin1
刊名MATERIALS & DESIGN
出版日期2017-01-15
卷号114页码:161-166
关键词MXene Bifluoride Ti3C2 Multilayer structure Ceramics
英文摘要MXene, a new family of 2D materials, possesses excellent electrical conductivity and hydrophilicity. To date, the majority of MXenes are only successfully produced by exfoliating the MAX phases with high concentration hydrofluoric acid (HF). In this study, the 2D MXene Ti3C2 with larger interplanar spacing was successfully obtained by etching Ti3AlC2 with bifluoride (NaHF2, KHF2, NH4HF2) in single-stage process. The morphology, structure and element composition of prepared Ti3C2 samples were characterized by scanning electrons microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive spectrometer (EDS). The synthesis mechanism of Ti3C2 was elaborately demonstrated. The possible reaction equations between Ti3AlC2 and different bifluorides were generalized, indicating the formation of hydrosoluble by-products of Na3AlF6, K3AlF6 and (NH4)(3)AlF6. This work presents a safely effective method to synthesize the 2D nanocrystals MXene. (C) 2016 Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Technology
类目[WOS]Materials Science, Multidisciplinary
研究领域[WOS]Materials Science
关键词[WOS]HIGH VOLUMETRIC CAPACITANCE ; LI-ION BATTERIES ; TITANIUM CARBIDE ; THERMAL-STABILITY ; STORAGE ; COMPOSITES ; ANODE ; INTERCALATION ; ELECTROLYTE ; PERFORMANCE
收录类别SCI
语种英语
WOS记录号WOS:000390650800020
源URL[http://ir.sic.ac.cn/handle/331005/21919]  
专题上海硅酸盐研究所_特种无机涂层重点实验室_期刊论文
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Coating Mat, Shanghai 200050, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Feng, Aihu,Yu, Yun,Wang, Yong,et al. Two-dimensional MXene Ti3C2 produced by exfoliation of Ti3AlC2[J]. MATERIALS & DESIGN,2017,114:161-166.
APA Feng, Aihu.,Yu, Yun.,Wang, Yong.,Jiang, Feng.,Yu, Yang.,...&Song, Lixin.(2017).Two-dimensional MXene Ti3C2 produced by exfoliation of Ti3AlC2.MATERIALS & DESIGN,114,161-166.
MLA Feng, Aihu,et al."Two-dimensional MXene Ti3C2 produced by exfoliation of Ti3AlC2".MATERIALS & DESIGN 114(2017):161-166.

入库方式: OAI收割

来源:上海硅酸盐研究所

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