Zn(II)-PEG 300 Globules as Soft Template for the Synthesis of Hexagonal ZnO Micronuts by the Hydrothermal Reaction Method
文献类型:期刊论文
作者 | Shi Xixi; Pan Lingling; Chen Shuoping; Xiao Yong; Liu Qiaoyun; Yuan Liangjie; Sun Jutang; Cai Lintao |
刊名 | LANGMUIR
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出版日期 | 2009 |
卷号 | 20期号:10页码:5940-5948 |
英文摘要 | Hexagonal ZnO micronuts (HZMNs) have been successfully synthesized with the assistance of poly(ethylene glycol) (PEG) 300 via a hydrothermal method. The structure and morphology of the HZMNs were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and selected area electron diffraction (SAED). An individual ZnO micronut is revealed as twinned crystals. Time-dependent investigation shows that the growth of HZMNs involves a dissolution-recrystallization process followed by Ostwald ripening, in which is the first formed solid ZnO particles dissolve and transform to HZMNs with hollow structure. PEG 300 has been found to play a crucial role in the growth of this unique hollow structure. TEM observations show that the PEG chains aggregate to globules in water, which then have interaction with the dissolved zinc species to form the globules in a coiled state under hydrothermal conditions. These Zn(II)-PEG 300 globules act as soft template for the growth of HZMNs, and the possible growth mechanism is proposed. The room-temperature photoluminescence (PL) spectrum shows red emission around 612 nm with a full width at half-maximum (fwhm) only about 13 nm. |
收录类别 | SCI |
原文出处 | http://www.ncbi.nlm.nih.gov/pubmed/19388644 |
语种 | 英语 |
源URL | [http://ir.siat.ac.cn:8080/handle/172644/2544] ![]() |
专题 | 深圳先进技术研究院_医工所 |
作者单位 | LANGMUIR |
推荐引用方式 GB/T 7714 | Shi Xixi,Pan Lingling,Chen Shuoping,et al. Zn(II)-PEG 300 Globules as Soft Template for the Synthesis of Hexagonal ZnO Micronuts by the Hydrothermal Reaction Method[J]. LANGMUIR,2009,20(10):5940-5948. |
APA | Shi Xixi.,Pan Lingling.,Chen Shuoping.,Xiao Yong.,Liu Qiaoyun.,...&Cai Lintao.(2009).Zn(II)-PEG 300 Globules as Soft Template for the Synthesis of Hexagonal ZnO Micronuts by the Hydrothermal Reaction Method.LANGMUIR,20(10),5940-5948. |
MLA | Shi Xixi,et al."Zn(II)-PEG 300 Globules as Soft Template for the Synthesis of Hexagonal ZnO Micronuts by the Hydrothermal Reaction Method".LANGMUIR 20.10(2009):5940-5948. |
入库方式: OAI收割
来源:深圳先进技术研究院
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