LiRb2LaB2O6: a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge
文献类型：期刊论文
| 作者 | Xu, DD (Xu, Dongdong); Zhang, FF (Zhang, Fangfang) ; Sun, YZ (Sun, Yanzhou); Yang, ZH (Yang, Zhihua); Lei, BH (Lei, Binghua); Liu, LL (Liu, Lili); Pan, SL (Pan, Shilie)
|
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2017 |
| 卷号 | 46期号:1页码:193-199 |
| 通讯作者 | Zhang, FF |
| 英文摘要 | A new rare-earth borate LiRb2LaB2O6 (LB-1) has been synthesized using a high-temperature solution method. Interestingly, it shares its topological structure with the famous porous material MOF-5, which is formed from Zn4O(BDC)(3) (BDC = 1,4-benzenedicarboxylate). The nodes [OZn4] and organic linkers [BDC] of MOF-5 are carefully substituted with La3+ rare-earth cations and the inorganic linkers [BO3] and [LiO4], respectively, in order to construct a pure inorganic open framework. LB-1 exhibits good thermal and water stability. Moreover, it possesses a short cut-off edge (<190 nm) and moderate birefringence (exp. 0.040@589.5 nm, cal. 0.038@589.5 nm). Further insights into the cut-off edge were given by first-principles calculations. The factors that influence the birefringence of LB-1 were discussed in view of the spatial arrangement of the [BO3] anionic groups. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000391570700022 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4724]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, DD ,Zhang, FF ,Sun, YZ ,et al. LiRb2LaB2O6: a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge[J]. DALTON TRANSACTIONS,2017,46(1):193-199. |
| APA | Xu, DD .,Zhang, FF .,Sun, YZ .,Yang, ZH .,Lei, BH .,...&Pan, SL .(2017).LiRb2LaB2O6: a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge.DALTON TRANSACTIONS,46(1),193-199. |
| MLA | Xu, DD ,et al."LiRb2LaB2O6: a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge".DALTON TRANSACTIONS 46.1(2017):193-199. |
入库方式： OAI收割
来源：新疆理化技术研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。