Effect of solubility of a hydrazide compound on the crystallization behavior of poly(L-lactide)
文献类型：期刊论文
| 作者 | Xing, Qian1; Wang, Zefan2; Li, Rongbo3; Dong, Xia2; Wang, Dujin2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:114页码:113377-113389 |
| 英文摘要 | Tetramethylenedicarboxylic di-(2-hydroxybenzohydrazide) (TMBH) has been proved to be an effective nucleating agent for poly ((L)-lactide) (PLLA). The correlation between the solubility of TMBH in a PLLA melt during the annealing treatment and its nucleating efficiency has been systematically investigated. The phase diagrams of the binary system consisting of PLLA and TMBH were constructed by differential scanning calorimetry and polarized optical microscopy. Depending on the annealing temperature (T-f) and TMBH concentration (C-TMBH), TMBH may remain crystallites, or partially/completely dissolve into a PLLA melt, which greatly affected the crystallization kinetics and crystalline morphology of PLLA. When Tf was relatively lower and/or TMBH concentration was higher, TMBH crystallites remained solid in the PLLA melt after annealing treatment (e.g. T-f@ 180 degrees C and C-TMBH@1 wt%), which could effectively enhance the crystallization rate and nucleation density of PLLA. The solubility of TMBH in the PLLA melt would be increased gradually with the increase of T-f and/or the decrease of CTMBH, e.g. TMBH would be partially dissolved into the PLLA melt for TMBH-1 at 200 degrees C. Furthermore, TMBH would be completely dissolved into the PLLA melt as T-f was raised to 230 degrees C with CTMBH ranging from 0.1 to 1 wt%. In this case, the soluble TMBH molecules would assemble into rod-like structures with lower specific area during the cooling process, which decreased the nucleating efficiency of TMBH and produced rod-like PLLA crystallites. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36430]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Beijing Technol & Business Univ, Sch Mat Sci & Mech Engn, Beijing 100048, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China 3.Petrochina Petrochem Res Inst, Beijing 102206, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xing, Qian,Wang, Zefan,Li, Rongbo,et al. Effect of solubility of a hydrazide compound on the crystallization behavior of poly(L-lactide)[J]. RSC ADVANCES,2016,6(114):113377-113389. |
| APA | Xing, Qian,Wang, Zefan,Li, Rongbo,Dong, Xia,&Wang, Dujin.(2016).Effect of solubility of a hydrazide compound on the crystallization behavior of poly(L-lactide).RSC ADVANCES,6(114),113377-113389. |
| MLA | Xing, Qian,et al."Effect of solubility of a hydrazide compound on the crystallization behavior of poly(L-lactide)".RSC ADVANCES 6.114(2016):113377-113389. |
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来源：化学研究所
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