Preparation of nanosilica-immobilized antioxidant and the antioxidative behavior in low density polyethylene
文献类型：期刊论文
| 作者 | Liu, Peng; Tang, Hanying; Lu, Ming; Gao, Chong; Wang, Feng; Ding, Yanfen; Zhang, Shimin; Yang, Mingshu |
| 刊名 | POLYMER DEGRADATION AND STABILITY
 |
| 出版日期 | 2017 |
| 卷号 | 135页码:1-7 |
| 关键词 | Silica Antioxidant Low density polyethylene Thermal oxidative stability |
| 英文摘要 | This article reports a study of the preparation of nanosilica-immobilized antioxidant (SiO2-APTMS-AO) and the thermal oxidative stability of low density polyethylene (LDPE) nanocomposites containing SiO2-APTMS-AO. SiO2-APTMS-AO was prepared based on the fumed nanosilica which was firstly modified with an aminosilane coupling agent and then reacted with 3,5-Di-tert-butyl-4-hydroxybenzoic acyl chloride. Infrared spectroscopy, X-ray photoelectron spectroscopy and thermogravimetric analysis measurements confirmed that the antioxidant group was chemically immobilized onto nanosilica. LDPE/silica nanocomposites were prepared by melt mixing and then pressed into different films. The thermal oxidative stability of the nanocomposites was evaluated by thermogravimetric analysis in air atmosphere, oxidation induction time (OIT) and long-term accelerated thermal aging. The results showed that the SiO2-APTMS-AO can significant improve the thermal oxidative stability of LDPE nanocomposite. Because SiO2-APTMS-AO is based on inorganic nano-filler, in comparison to organic antioxidants, it might have advantages in thermal stability and migration stability during processing and application. (C) 2016 Elsevier Ltd. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36538]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Peng,Tang, Hanying,Lu, Ming,et al. Preparation of nanosilica-immobilized antioxidant and the antioxidative behavior in low density polyethylene[J]. POLYMER DEGRADATION AND STABILITY,2017,135:1-7. |
| APA | Liu, Peng.,Tang, Hanying.,Lu, Ming.,Gao, Chong.,Wang, Feng.,...&Yang, Mingshu.(2017).Preparation of nanosilica-immobilized antioxidant and the antioxidative behavior in low density polyethylene.POLYMER DEGRADATION AND STABILITY,135,1-7. |
| MLA | Liu, Peng,et al."Preparation of nanosilica-immobilized antioxidant and the antioxidative behavior in low density polyethylene".POLYMER DEGRADATION AND STABILITY 135(2017):1-7. |
入库方式： OAI收割
来源：化学研究所
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