Efficient hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over a cobalt and copper bimetallic catalyst on N-graphene-modified Al2O3
文献类型：期刊论文
| 作者 | Guo, Weiwei1,2; Liu, Hangyu1,2; Zhang, Suqi1; Han, Hongling1,2; Liu, Huizhen1,2; Jiang, Tao1; Han, Buxing1,2; Wu, Tianbin1 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2016 |
| 卷号 | 18期号:23页码:6222-6228 |
| 英文摘要 | 2,5-Dimethylfuran (DMF) is an important candidate for liquid fuels and can be produced from biomass derived 5-hydroxymethylfurfural (HMF). Efficient transformation of HMF to DMF has not been achieved over a non-noble catalyst under milder conditions. Herein, we developed a copper and cobalt bimetallic nanoparticle catalyst supported on N-graphene-modified Al2O3 (CuCo (R)/NGr/alpha-Al2O3). It was found that CuCo (R)/NGr/alpha-Al2O3 could catalyze the conversion of HMF to DMF effectively and the yield of DMF could reach 99%. The catalyst was completely not active for the hydrogenation of the CvC bond in furan and thus no 2,5-bis (hydroxymethyl) tetrahydrofuran (DHTHF) and 2,5-dimethyltetrahydrofuran (DMTHF) were detected. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36518]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Weiwei,Liu, Hangyu,Zhang, Suqi,et al. Efficient hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over a cobalt and copper bimetallic catalyst on N-graphene-modified Al2O3[J]. GREEN CHEMISTRY,2016,18(23):6222-6228. |
| APA | Guo, Weiwei.,Liu, Hangyu.,Zhang, Suqi.,Han, Hongling.,Liu, Huizhen.,...&Wu, Tianbin.(2016).Efficient hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over a cobalt and copper bimetallic catalyst on N-graphene-modified Al2O3.GREEN CHEMISTRY,18(23),6222-6228. |
| MLA | Guo, Weiwei,et al."Efficient hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over a cobalt and copper bimetallic catalyst on N-graphene-modified Al2O3".GREEN CHEMISTRY 18.23(2016):6222-6228. |
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来源：化学研究所
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