11.4% Efficiency non-fullerene polymer solar cells with trialkylsilyl substituted 2D-conjugated polymer as donor
文献类型：期刊论文
| 作者 | Bin, Haijun1,2; Gao, Liang1,2; Zhang, Zhi-Guo1; Yang, Yankang1,2; Zhang, Yindong3,4,5; Zhang, Chunfeng3,4,5; Chen, Shanshan6; Xue, Lingwei1; Yang, Changduk6; Xiao, Min3,4,5 |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2016-12-01 |
| 卷号 | 7 |
| 英文摘要 | Simutaneously high open circuit voltage and high short circuit current density is a big challenge for achieving high efficiency polymer solar cells due to the excitonic nature of organic semdonductors. Herein, we developed a trialkylsilyl substituted 2D-conjugated polymer with the highest occupied molecular orbital level down-shifted by Si-C bond interaction. The polymer solar cells obtained by pairing this polymer with a non-fullerene acceptor demonstrated a high power conversion efficiency of 11.41% with both high open circuit voltage of 0.94 V and high short circuit current density of 17.32 mA cm(-2) benefitted from the complementary absorption of the donor and acceptor, and the high hole transfer efficiency from acceptor to donor although the highest occupied molecular orbital level difference between the donor and acceptor is only 0.11 eV. The results indicate that the alkylsilyl substitution is an effective way in designing high performance conjugated polymer photovoltaic materials. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36515]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Nanjing Univ, Sch Phys, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China 4.Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China 5.Univ Sci & Technol China, Synerget Innovat Ctr Quantum Informat & Quantum P, Hefei 230026, Anhui, Peoples R China 6.Ulsan Natl Inst Sci & Technol, Sch Energy & Chem Engn, Dept Energy Engn, Low Dimens Carbon Mat Ctr, Ulsan 689798, South Korea 7.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Lab Adv Optoelect Mat, State & Local Joint Engn Lab Novel Funct Polymer, Suzhou 215123, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bin, Haijun,Gao, Liang,Zhang, Zhi-Guo,et al. 11.4% Efficiency non-fullerene polymer solar cells with trialkylsilyl substituted 2D-conjugated polymer as donor[J]. NATURE COMMUNICATIONS,2016,7. |
| APA | Bin, Haijun.,Gao, Liang.,Zhang, Zhi-Guo.,Yang, Yankang.,Zhang, Yindong.,...&Li, Yongfang.(2016).11.4% Efficiency non-fullerene polymer solar cells with trialkylsilyl substituted 2D-conjugated polymer as donor.NATURE COMMUNICATIONS,7. |
| MLA | Bin, Haijun,et al."11.4% Efficiency non-fullerene polymer solar cells with trialkylsilyl substituted 2D-conjugated polymer as donor".NATURE COMMUNICATIONS 7(2016). |
入库方式： OAI收割
来源：化学研究所
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