Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction
文献类型：期刊论文
| 作者 | Guo, Xiaoling1,2; Qi, Wei2; Liu, Wei2; Liang, Changhai1; Zheng, Anmin3; Yi, Xianfeng3; Su, Dangsheng2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:101页码:99570-99576 |
| 英文摘要 | A series of conjugated polymers (YPB-x) with designated chemical structure are synthesized as model carbon catalysts for mechanistic and kinetic studies of nitroaromatic reduction reactions. The reaction kinetics show that ketonic carbonyl groups are active sites for the nitrobenzene (NB) reduction. A catalytic reaction mechanism involving the activation of hydrazine with carbon catalysts and the subsequent reduction of NB is proposed to describe the catalytic process molecularly. The turnover frequency of heterogeneous carbon catalysts in the liquid phase is reported for the fair comparison of the intrinsic activity among different carbon catalysts. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | OXIDATIVE DEHYDROGENATION ; HETEROGENEOUS CATALYST ; NITROBENZENE ; HYDROGENATION ; POLYMERIZATION ; CARBOCATALYSIS ; ETHYLBENZENE ; NANOCARBON ; HYDRAZINE ; CHEMISTRY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000387427800121 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/9969]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Xiaoling,Qi, Wei,Liu, Wei,et al. Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction[J]. RSC ADVANCES,2016,6(101):99570-99576. |
| APA | Guo, Xiaoling.,Qi, Wei.,Liu, Wei.,Liang, Changhai.,Zheng, Anmin.,...&Su, Dangsheng.(2016).Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction.RSC ADVANCES,6(101),99570-99576. |
| MLA | Guo, Xiaoling,et al."Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction".RSC ADVANCES 6.101(2016):99570-99576. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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