Design and synthesis of micro-meso-macroporous polymers with versatile active sites and excellent activities in the production of biofuels and fine chemicals
文献类型：期刊论文
| 作者 | Liu, Fujian1,2; Liu, Chen1; Kong, Weiping1; Qi, Chenze1; Zheng, Anmin3; Dai, Sheng2,4 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2016 |
| 卷号 | 18期号:24页码:6536-6544 |
| 英文摘要 | Micro-meso-macroporous polymers (MOPs) grafted with versatile functional groups, such as sulfonate, amine, triazole, pyridine, strong acidic ionic liquids and triphenylphosphine, were synthesized by in situ cross-linking of different functional molecules with 1,4-bis(chloromethyl) benzene in the presence of Lewis acid catalysts without using additional templates. The resultant hyper-cross-linked nanoporous polymers show unique characteristics such as large BET surface areas (up to 1523 m(2) g(-1)), abundant micro-meso-macropores (4.5-131 nm), and tunable and versatile active sites (acid, base and palladium). These functional polymers exhibit excellent activities and good reusability in biomass conversions, cross-coupling reactions and condensation. The catalytic activities are much better than those of various conventional catalysts such as H3PW12O40, SBA-15-SO3H, Amberlyst 15, and mesoporous H-ZSM-5 Pd/C and even as comparable as those of homogeneous H2SO4 and HCl in the depolymerization of crystalline cellulose into fine chemicals and towards transesterification to biodiesel. This work highlights a low cost route to the synthesis of solid catalysts based on functional nanoporous polymers for catalyzing the production of clean biofuels and fine chemicals. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | COVALENT ORGANIC FRAMEWORKS ; ORDERED MESOPOROUS POLYMERS ; SOLID ACID CATALYSTS ; IONIC LIQUIDS ; NANOPOROUS POLYMERS ; CARBON FRAMEWORKS ; COUPLING REACTION ; CELLULOSE ; TEMPLATES ; EFFICIENT |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000389341800014 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/9991]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Shaoxing Univ, Coll Chem & Chem Engn, Shaoxing 312000, Peoples R China 2.Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA 3.Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 4.Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37831 USA |
| 推荐引用方式 GB/T 7714 | Liu, Fujian,Liu, Chen,Kong, Weiping,et al. Design and synthesis of micro-meso-macroporous polymers with versatile active sites and excellent activities in the production of biofuels and fine chemicals[J]. GREEN CHEMISTRY,2016,18(24):6536-6544. |
| APA | Liu, Fujian,Liu, Chen,Kong, Weiping,Qi, Chenze,Zheng, Anmin,&Dai, Sheng.(2016).Design and synthesis of micro-meso-macroporous polymers with versatile active sites and excellent activities in the production of biofuels and fine chemicals.GREEN CHEMISTRY,18(24),6536-6544. |
| MLA | Liu, Fujian,et al."Design and synthesis of micro-meso-macroporous polymers with versatile active sites and excellent activities in the production of biofuels and fine chemicals".GREEN CHEMISTRY 18.24(2016):6536-6544. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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