Degradation of Black Phosphorus: A Real-Time P-31 NMR Study
文献类型：期刊论文
| 作者 | Wang, Y; Yang, BC; Wan, BS(万本松); Xi, XK; Zeng, ZM(曾中明); Liu, EK; Wu, GH; Liu, ZY; Wang, WH |
| 刊名 | 2D MATERIALS
 |
| 出版日期 | 2016 |
| 卷号 | 3期号:3 |
| 通讯作者 | Xi, XK |
| 英文摘要 | In this work, degradation behaviors and mechanisms of black phosphorus (BP) crystals in air under ambient conditions were investigated by nuclear magnetic resonance spectroscopy. It has been found that the P-31 NMR line intensity for BP decreases exponentially during aging even at the very first several hours, suggesting the origin of the degradation of transport properties. In addition to phosphoric acid, new phosphorous acid was also well resolved in the final aging products. Moreover, BP has been found to be stable in water without the presence of oxygen molecules. These findings are relevant for better understanding of degradation behaviors of BP upon aging and should be helpful for overcoming a barrier that might hamper progress toward applications of BP as a 2D material. |
| 关键词[WOS] | EXFOLIATION ; TRANSISTORS ; ACCESS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000385420600004 |
| 源URL | [http://ir.sinano.ac.cn/handle/332007/4654]  |
| 专题 | 苏州纳米技术与纳米仿生研究所_纳米加工公共平台 |
| 推荐引用方式 GB/T 7714 | Wang, Y,Yang, BC,Wan, BS,et al. Degradation of Black Phosphorus: A Real-Time P-31 NMR Study[J]. 2D MATERIALS,2016,3(3). |
| APA | Wang, Y.,Yang, BC.,Wan, BS.,Xi, XK.,Zeng, ZM.,...&Wang, WH.(2016).Degradation of Black Phosphorus: A Real-Time P-31 NMR Study.2D MATERIALS,3(3). |
| MLA | Wang, Y,et al."Degradation of Black Phosphorus: A Real-Time P-31 NMR Study".2D MATERIALS 3.3(2016). |
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