An Imaging Ellipsometry Approach to Dissolved Oxygen Measurement on Surface Tethered Weak Polyelectrolyte Modified Electrode
文献类型:期刊论文
作者 | Liu, W; Li, M; Lv, B; Chen, YY(陈艳艳); Ma, HW(马宏伟); Viana, AS; Correia, JP; Jin, G |
刊名 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
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出版日期 | 2016 |
卷号 | 163期号:5 |
通讯作者 | Jin, G |
英文摘要 | Electro - total internal reflection ellipsometry has been reported as a phase sensitive ellipsometry technique to observe the redox reactions on the surface of the electrode. In this work, with the imaging ellipsometry, we have used Electro-total internal reflection imaging ellipsometry (Electro-TIRIE) to measure the dissolved oxygen concentration on the surface tethered weak polyelectrolyte brush, carboxylated poly(oligo(ethylene glycol) methacrylate-random-2-hydroxyethylmethacrylate), modified electrode. The cyclic voltammetry has shown despite the covering of the weak polyelectrolyte brush, the electrode could still reduce the dissolved oxygen and Electro-TIRIE technique could unveil the different swelling behavior of the brushes during the reduction. The difference may be attributed to the electro-active probe permeability of the brushes. With the imaging ellipsometry, we proposed a parallel dissolved oxygen measurement. Compared with our previous results, the optical signal noise ratio has been enhanced 10 times and the measurement time has reduced from 30 minutes to 10 minutes. (C) 2016 The Electrochemical Society. All rights reserved. |
关键词[WOS] | INTERNAL-REFLECTION ELLIPSOMETRY ; POLYMER BRUSHES ; BIOSENSOR ; COEFFICIENTS ; SENSOR ; FILM |
收录类别 | SCI ; EI |
语种 | 英语 |
WOS记录号 | WOS:000370866700107 |
源URL | [http://ir.sinano.ac.cn/handle/332007/4774] ![]() |
专题 | 苏州纳米技术与纳米仿生研究所_纳米生物医学与安全研究部_马宏伟团队 |
推荐引用方式 GB/T 7714 | Liu, W,Li, M,Lv, B,et al. An Imaging Ellipsometry Approach to Dissolved Oxygen Measurement on Surface Tethered Weak Polyelectrolyte Modified Electrode[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2016,163(5). |
APA | Liu, W.,Li, M.,Lv, B.,Chen, YY.,Ma, HW.,...&Jin, G.(2016).An Imaging Ellipsometry Approach to Dissolved Oxygen Measurement on Surface Tethered Weak Polyelectrolyte Modified Electrode.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,163(5). |
MLA | Liu, W,et al."An Imaging Ellipsometry Approach to Dissolved Oxygen Measurement on Surface Tethered Weak Polyelectrolyte Modified Electrode".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 163.5(2016). |
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