Self-assembly of achiral monomer into left-handed helical polyanthracene nanofibers
文献类型：期刊论文
| 作者 | Han, B; Shen, FP; Su, H; Zhang, X; Shen, Y; Zhang, T(张珽) |
| 刊名 | MATERIALS EXPRESS
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:1 |
| 通讯作者 | Zhang, T(张珽) ; Shen, Y |
| 英文摘要 | Bionic control over the assembly of achiral molecules into chiral supramolecular architectures is challenging, and typically relies on preexisting templates. We demonstrated that anthracene monomers could self-assemble into polyanthracene (PA) nanofibers with well-defined left-handed helical nanoarchitectures under well-controlled conditions. The spontaneous formation of supramolecular helices might be ascribed to the steric constraints imposed by dehydrocyclization carried out at the 4,8 sites of the benzene ring of the anthracene monomer. Furthermore, high quality, few-layer graphene, derived from the chiral helical PA nanofibers, provided promising prospects and new ideas for functional materials synthesis and chirality amplification. |
| 关键词[WOS] | POLYANILINE NANOFIBERS ; THIN-FILMS ; POLYMERIZATION ; ANTHRACENE ; GRAPHENE ; FABRICATION ; COLLOIDS ; COMPLEX ; SENSORS |
| 收录类别 | SCI ; EI |
| 语种 | 英语 |
| WOS记录号 | WOS:000371194100012 |
| 源URL | [http://ir.sinano.ac.cn/handle/332007/4872]  |
| 专题 | 苏州纳米技术与纳米仿生研究所_纳米研究国际实验室_张珽团队 |
| 推荐引用方式 GB/T 7714 | Han, B,Shen, FP,Su, H,et al. Self-assembly of achiral monomer into left-handed helical polyanthracene nanofibers[J]. MATERIALS EXPRESS,2016,6(1). |
| APA | Han, B,Shen, FP,Su, H,Zhang, X,Shen, Y,&Zhang, T.(2016).Self-assembly of achiral monomer into left-handed helical polyanthracene nanofibers.MATERIALS EXPRESS,6(1). |
| MLA | Han, B,et al."Self-assembly of achiral monomer into left-handed helical polyanthracene nanofibers".MATERIALS EXPRESS 6.1(2016). |
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