Synthesis, Crystal Structure, and Electrochemical Properties of a Simple Magnesium Electrolyte for Magnesium/Sulfur Batteries
文献类型：期刊论文
| 作者 | Li, WF(李宛飞); Cheng, S(程双); Wang, J; Qiu, YC(丘勇才); Zheng, ZZ(郑召召); Lin, HZ(蔺洪振); Nanda, S; Ma, Q; Xu, Y; Ye, FM(叶方敏) |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016 |
| 卷号 | 55期号:22 |
| 通讯作者 | Zhang, YG(张跃钢) |
| 英文摘要 | Most simple magnesium salts tend to passivate the Mg metal surface too quickly to function as electrolytes for Mg batteries. In the present work, an electroactive salt [Mg-(THF)(6)][AlCl4](2) was synthesized and structurally characterized. The Mg electrolyte based on this simple mononuclear salt showed a high Mg cycling efficiency, good anodic stability (2.5V vs. Mg), and high ionic conductivity (8.5 mScm(-1)). Magnesium/sulfur cells employing the as-prepared electrolyte exhibited good cycling performance over 20 cycles in the range of 0.3-2.6 V, thus indicating an electrochemically reversible conversion of S to MgS without severe passivation of the Mg metal electrode surface. |
| 关键词[WOS] | RECHARGEABLE MG BATTERIES ; LITHIUM-SULFUR BATTERIES ; LI-S BATTERIES ; PERFORMANCE ; GRAPHENE ; SEPARATOR ; SALTS |
| 收录类别 | SCI ; EI |
| 语种 | 英语 |
| WOS记录号 | WOS:000377921200006 |
| 源URL | [http://ir.sinano.ac.cn/handle/332007/4800]  |
| 专题 | 苏州纳米技术与纳米仿生研究所_纳米研究国际实验室_张跃钢团队 |
| 推荐引用方式 GB/T 7714 | Li, WF,Cheng, S,Wang, J,et al. Synthesis, Crystal Structure, and Electrochemical Properties of a Simple Magnesium Electrolyte for Magnesium/Sulfur Batteries[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(22). |
| APA | Li, WF.,Cheng, S.,Wang, J.,Qiu, YC.,Zheng, ZZ.,...&Zhang, YG.(2016).Synthesis, Crystal Structure, and Electrochemical Properties of a Simple Magnesium Electrolyte for Magnesium/Sulfur Batteries.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(22). |
| MLA | Li, WF,et al."Synthesis, Crystal Structure, and Electrochemical Properties of a Simple Magnesium Electrolyte for Magnesium/Sulfur Batteries".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.22(2016). |
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