Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes
文献类型：期刊论文
| 作者 | Cao, RW; Zhang, JL; Zhou, H; Yang, HM; Jiang, GX(蒋高喜) |
| 刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY
 |
| 出版日期 | 2016 |
| 卷号 | 14期号:7 |
| 通讯作者 | Jiang, GX |
| 英文摘要 | A highly atom-economical allylation of oxindoles with vinyl cyclopropanes catalyzed by Pd(PPh3)(4) has been developed, setting up a practical venue for the installation of an all-carbon quaternary center at the 3-position in oxindoles under mild reaction conditions. Importantly, the reaction proceeded well without any additives and no waste was produced, affording linear products with high regioselectivities (>20:1). Enantioselective allylic alkylation has also been realized to provide the desired products in good yields and 35% ee. |
| 关键词[WOS] | ENANTIOSELECTIVE 3+2 CYCLOADDITION ; ASYMMETRIC ALLYLIC ALKYLATION ; DONOR-ACCEPTOR CYCLOPROPANES ; BAYLIS-HILLMAN ADDUCTS ; DIPHOSPHINE LIGANDS ; SYNTHETIC REACTIONS ; ALLYLBORONIC ACIDS ; VINYLCYCLOPROPANES ; CONSTRUCTION ; NUCLEOPHILES |
| 收录类别 | SCI ; EI |
| 语种 | 英语 |
| WOS记录号 | WOS:000370878800006 |
| 源URL | [http://ir.sinano.ac.cn/handle/332007/4925]  |
| 专题 | 苏州纳米技术与纳米仿生研究所_先进材料研究部_离职团队 |
| 推荐引用方式 GB/T 7714 | Cao, RW,Zhang, JL,Zhou, H,et al. Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2016,14(7). |
| APA | Cao, RW,Zhang, JL,Zhou, H,Yang, HM,&Jiang, GX.(2016).Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes.ORGANIC & BIOMOLECULAR CHEMISTRY,14(7). |
| MLA | Cao, RW,et al."Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes".ORGANIC & BIOMOLECULAR CHEMISTRY 14.7(2016). |
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