Multifunctions of Net Surface Charge in the Reaction on a Single Nanoparticle
文献类型：期刊论文
| 作者 | Xi, SB(席少波); Zhou, XC(周小春) |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2016 |
| 卷号 | 120期号:30 |
| 通讯作者 | Zhou, XC(周小春) |
| 英文摘要 | Electric charge can determine where and how reaction occurs, but the relationship between net surface charge and activity is unclear because of the difficulty in simultaneously detecting charge and activity at the single nanoparticle level. In this study, we use ions as probes to detect the distribution of net surface charge and track galvanic replacement reaction on single Ag nanowire in situ and in real time by dark-field microscopy. The two ends of a single Ag nanowire are found to possess more net surface charges than the middle part. The unevenly distributed net surface charge performs multifunctions in determining the reaction activity, selectivity, and product shape. Owing to the interaction between the net surface charges and ions in solution, many clusters are generated on the Ag nanowires. The locations of generating these clusters are where faster deposition reaction happens. Furthermore, larger size Ag compounds with clear shape are produced near the two ends by attracting Ag+ at lower [HAuCl4], but larger size Ag-Au alloy clusters with veiled shape are produced near the center by repelling AuCl4- at higher [HAuCl4]. Given that net surface charge generally exists in nanoscience, the methodology and results obtained from this research can be widely used in other single-shaped nanomaterials. |
| 关键词[WOS] | UNIFORM SILVER NANOWIRES ; GALVANIC REPLACEMENT ; METAL NANOSTRUCTURES ; OPTICAL-PROPERTIES ; RANDOM NUCLEATION ; FACILE SYNTHESIS ; GOLD NANOCAGES ; GROWTH ; MICROSCOPY ; NANOTUBES |
| 收录类别 | SCI ; EI |
| 语种 | 英语 |
| WOS记录号 | WOS:000381236100037 |
| 源URL | [http://ir.sinano.ac.cn/handle/332007/4628]  |
| 专题 | 苏州纳米技术与纳米仿生研究所_先进材料研究部_周小春团队 |
| 推荐引用方式 GB/T 7714 | Xi, SB,Zhou, XC. Multifunctions of Net Surface Charge in the Reaction on a Single Nanoparticle[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2016,120(30). |
| APA | Xi, SB,&Zhou, XC.(2016).Multifunctions of Net Surface Charge in the Reaction on a Single Nanoparticle.JOURNAL OF PHYSICAL CHEMISTRY C,120(30). |
| MLA | Xi, SB,et al."Multifunctions of Net Surface Charge in the Reaction on a Single Nanoparticle".JOURNAL OF PHYSICAL CHEMISTRY C 120.30(2016). |
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