Solid-phase extraction-stepwise elution (SPE-SE) procedure for isolation of dissolved organic matter prior to ESI-FT-ICR-MS analysis
文献类型：期刊论文
| 作者 | Lv, Jitao; Zhang, Shuzhen; Luo, Lei; Cao, Dong |
| 刊名 | ANALYTICA CHIMICA ACTA
 |
| 出版日期 | 2016-12-15 |
| 卷号 | 948期号:0页码:55-61 |
| 关键词 | DOM SPE ESI-FT-ICR-MS Stepwise elution |
| 英文摘要 | Characterization of dissolved organic matter (DOM) at the molecular level will greatly improve our understanding of its bio-geochemical role in controlling the fate of contaminants in the environment, and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) is the most powerful analytical technique for this purpose. Before FT-ICR-MS analysis, isolation, desalination and concentration of DOM are necessary, and solid-phase extraction (SPE) is the most widely applied pretreatment procedure. However, some molecular information is lost using conventional SPE methods. Here, we propose a novel strategy of SPE enrichment using stepwise elution (SPE-SE). Compounds in DOM were divided into three fractions by this SPE-SE procedure according to their polarity and ionization efficiency. The diversity of DOM molecules identified by ESI-FT-ICR-MS using SPE-SE exceeded those using conventional SPE methods by more than 50%. This method is feasible and has the potential to be used as a pretreatment strategy for complex DOM matrixes prior to ESI-FT-ICR-MS analysis, especially for those rich in nitrogenous molecules, carbohydrates, lipids and/or aromatic compounds. (C) 2016 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/35948]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Lv, Jitao,Zhang, Shuzhen,Luo, Lei,et al. Solid-phase extraction-stepwise elution (SPE-SE) procedure for isolation of dissolved organic matter prior to ESI-FT-ICR-MS analysis[J]. ANALYTICA CHIMICA ACTA,2016,948(0):55-61. |
| APA | Lv, Jitao,Zhang, Shuzhen,Luo, Lei,&Cao, Dong.(2016).Solid-phase extraction-stepwise elution (SPE-SE) procedure for isolation of dissolved organic matter prior to ESI-FT-ICR-MS analysis.ANALYTICA CHIMICA ACTA,948(0),55-61. |
| MLA | Lv, Jitao,et al."Solid-phase extraction-stepwise elution (SPE-SE) procedure for isolation of dissolved organic matter prior to ESI-FT-ICR-MS analysis".ANALYTICA CHIMICA ACTA 948.0(2016):55-61. |
入库方式： OAI收割
来源：生态环境研究中心
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