Innovative photo-Fenton catalysis by PE-FeOx films leading to methylene blue (MB) degradation: Kinetics, surface properties and mechanism
文献类型：期刊论文
| 作者 | Suarez, Laura; Dong, Huiyu; Pulgarin, Cesar; Sanjines, Rosendo; Qiang, Zhimin; Kiwi, John |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2016-06-05 |
| 卷号 | 519期号:0页码:68-77 |
| 关键词 | PE-FeOx synthesis MB-discoloration Visible light XPS AFM XRD Repetitive MB degradation H2O2 Heterogeneous catalysis ROS diffusion distances |
| 英文摘要 | This study reports an innovative preparation polyethylene-FeOx (PE-FeOx films) leading to the degradation of the methylene blue (MB) dye under low intensity sunlight/visible light (>400 nm). The intermediate highly oxidative radicals generated by PE-FeOx leading to MB discoloration/degradation in the presence of H2O2 were identified. The relative contribution to the MB discoloration by the Fe ions leached from the PE-FeOx films into solution was determined quantitatively. This allows estimating the contribution of the heterogeneous and of the homogeneous leading to MB-degradation. The shift in the peak binding energy (BE) for Fe was detected by photoelectron spectroscopy (XPS) after the MB degradation providing the evidence for redox catalysis occurring during MB-degradation at the PE-FeOx surface. The particle size and roughness of the PE-FeOx surfaces were determined by atomic force spectroscopy (AFM). The spectral properties of PE-FeOx films are reported and insight is provided for the mechanism of MB-degradation. (C) 2016 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/36055]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Suarez, Laura,Dong, Huiyu,Pulgarin, Cesar,et al. Innovative photo-Fenton catalysis by PE-FeOx films leading to methylene blue (MB) degradation: Kinetics, surface properties and mechanism[J]. APPLIED CATALYSIS A-GENERAL,2016,519(0):68-77. |
| APA | Suarez, Laura,Dong, Huiyu,Pulgarin, Cesar,Sanjines, Rosendo,Qiang, Zhimin,&Kiwi, John.(2016).Innovative photo-Fenton catalysis by PE-FeOx films leading to methylene blue (MB) degradation: Kinetics, surface properties and mechanism.APPLIED CATALYSIS A-GENERAL,519(0),68-77. |
| MLA | Suarez, Laura,et al."Innovative photo-Fenton catalysis by PE-FeOx films leading to methylene blue (MB) degradation: Kinetics, surface properties and mechanism".APPLIED CATALYSIS A-GENERAL 519.0(2016):68-77. |
入库方式： OAI收割
来源：生态环境研究中心
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