Preparation of Interconnected Biomimetic Poly(vinylidene fluoride-co-chlorotrifluoroethylene) Hydrophobic Membrane by Tuning the Two-Stage Phase Inversion Process
文献类型：期刊论文
| 作者 | Zheng, Libing ; Wang, Jun; Wu, Zhenjun; Li, Jie; Zhang, Yong; Yang, Min; Wei, Yuansong
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| 刊名 | ACS APPLIED MATERIALS & INTERFACES
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| 出版日期 | 2016-11-30 |
| 卷号 | 8期号:47页码:32604-32615 |
| 关键词 | biomimetic membrane interconnectivity crystallization two-stage phase inversion exposure duration |
| 英文摘要 | A facile strategy was applied for poly(vinylidene fluoride-co-chlorotrifluoroethylene) (PVDF-CTFE) hydrophobic membrane preparation by tuning the two-stage phase inversion process. The exposure stage was found to benefit the solid-liquid demixing process (gelation/crystallization) induced by the solvent evaporation and the subsequent phase inversion induced by immersion benefit the liquid-liquid demixing. It was confirmed that the electrospun nanostructure-like biomimetic surface and interconnected pore structure can be expected by controlling the exposure duration, and 300 s was considered as the inflection point of exposure duration for PVDF-CTFE membrane through which a tremendous variation would show. The micro/nanohierarchical structure in the membrane surface owing to the crystallization of PVDF-CTFE copolymer was responsible for the improvement of membrane roughness and hydrophobicity. Meanwhile, the interconnected pore structure in both the surface and the cross-section, which were formed because of the crystallization process, offers more mass transfer passages and enhances the permeate flux. The membrane then showed excellent MD performance with high permeate flux, high salt rejection, and relatively high stability during a 48 h continuous DCMD operation, according to the morphology, pore structure, and properties, which can be a substitute for hydrophobic membrane application. |
| 收录类别 | SCI |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/36071]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zheng, Libing,Wang, Jun,Wu, Zhenjun,et al. Preparation of Interconnected Biomimetic Poly(vinylidene fluoride-co-chlorotrifluoroethylene) Hydrophobic Membrane by Tuning the Two-Stage Phase Inversion Process[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(47):32604-32615. |
| APA | Zheng, Libing.,Wang, Jun.,Wu, Zhenjun.,Li, Jie.,Zhang, Yong.,...&Wei, Yuansong.(2016).Preparation of Interconnected Biomimetic Poly(vinylidene fluoride-co-chlorotrifluoroethylene) Hydrophobic Membrane by Tuning the Two-Stage Phase Inversion Process.ACS APPLIED MATERIALS & INTERFACES,8(47),32604-32615. |
| MLA | Zheng, Libing,et al."Preparation of Interconnected Biomimetic Poly(vinylidene fluoride-co-chlorotrifluoroethylene) Hydrophobic Membrane by Tuning the Two-Stage Phase Inversion Process".ACS APPLIED MATERIALS & INTERFACES 8.47(2016):32604-32615. |
入库方式： OAI收割
来源：生态环境研究中心
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