Synthesis and structures of type-I clathrates: Rb6Na2Ge44.89(1), Cs6Na2Zn4Ge42 and Cs6.40(1)Na1.60(1)Ga8Ge38
文献类型：期刊论文
| 作者 | Zhang, Hui1,2,3; Mu, Gang1,2,3; Huang, Fuqiang3,4; Xie, Xiaoming1,2,3 |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2016-10-01 |
| 卷号 | 242页码:155-161 |
| 关键词 | Clathrates Structures Theoretical calculations |
| 英文摘要 | Type-I clathrates of Rb6Na2Ge44.89(1), Cs6Na2Zn4Ge42 and Cs-6.40Na1.60(1)Ga8Ge38 were synthesized via solid-state reaction. Rb6Na2Ge44.89(1), Cs6Na2Zn4Ge42 and Cs-6.40Na1.60(1)Ga8Ge38 were found to crystalize in the cubic space group of Pm3n with lattice parameters of a =10.72755(5) angstrom, a =10.79501(8) angstrom and a=10.79726(5) A, respectively. Theoretical calculations indicated semiconducting features for the calculation models of Rb6Na2Ge44, Cs6Na2Zn4Ge42 and Cs6Na2Ga8Ge38 with band gaps of 0.002 eV, 0297 eV and 0.221 eV, respectively. (C) 2016 Elsevier Inc. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | HIGH-PRESSURE SYNTHESIS ; DISORDER PHASE-TRANSITION ; P-TE SYSTEM ; CRYSTAL-STRUCTURE ; CATIONIC CLATHRATE ; GERMANIUM CLATHRATE ; PHYSICAL-PROPERTIES ; THERMOELECTRIC PROPERTIES ; THERMAL-CONDUCTIVITY ; TRANSPORT-PROPERTIES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000382429600021 |
| 源URL | [http://ir.sic.ac.cn/handle/331005/22855]  |
| 专题 | 上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Funct Mat Informat, Shanghai Inst Microsyst & Informat Technol, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Shanghai Ctr Superconduct, Shanghai Inst Microsyst & Informat Technol, Shanghai 200050, Peoples R China 3.CAS Ctr Excellence Superconducting Elect CENSE, Shanghai 200050, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Hui,Mu, Gang,Huang, Fuqiang,et al. Synthesis and structures of type-I clathrates: Rb6Na2Ge44.89(1), Cs6Na2Zn4Ge42 and Cs6.40(1)Na1.60(1)Ga8Ge38[J]. JOURNAL OF SOLID STATE CHEMISTRY,2016,242:155-161. |
| APA | Zhang, Hui,Mu, Gang,Huang, Fuqiang,&Xie, Xiaoming.(2016).Synthesis and structures of type-I clathrates: Rb6Na2Ge44.89(1), Cs6Na2Zn4Ge42 and Cs6.40(1)Na1.60(1)Ga8Ge38.JOURNAL OF SOLID STATE CHEMISTRY,242,155-161. |
| MLA | Zhang, Hui,et al."Synthesis and structures of type-I clathrates: Rb6Na2Ge44.89(1), Cs6Na2Zn4Ge42 and Cs6.40(1)Na1.60(1)Ga8Ge38".JOURNAL OF SOLID STATE CHEMISTRY 242(2016):155-161. |
入库方式： OAI收割
来源：上海硅酸盐研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。