中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hierarchical MnO2 Spheres Decorated by Carbon-Coated Cobalt Nanobeads: Low-Cost and High-Performance Electrode Materials for Supercapacitors

文献类型:期刊论文

作者Zhi, Jian1,2; Reiser, Oliver1; Huang, Fuqiang2,3,4
刊名ACS APPLIED MATERIALS & INTERFACES
出版日期2016-04-06
卷号8期号:13页码:8452-8459
关键词MnO2 spheres cobalt nanobeads low cost high performance symmetrical supercapacitor
英文摘要

MnO2 is a promising electrode material for supercapacitors, because it exhibits high theoretical specific capacitance (1380 F g(-1)) for electrical charge while also being inexpensive and environmentally benign. However, owing to its low electrical conductivity, the intrinsic pseudocapacity of is In MnO2 not fully utilized. this work, hierarchically structured spheres composed of MnO2 nanoplatelets and carbon coated cobalt nanobeads (MnO2-NPs@Co/C) are chosen as electrode materials for supercapacitor. With a Co/C mass loading of 19 wt %, the electrical conductivity of the hybrid is 122-fold larger than that of pristine MnO2, showing a specific capacitance of the constituent MnO2 as high as 1240 F g(-1), being close to the theoretical value. Such improved specific capacitance of MnO2-NPs@Co/C electrode is largely contributed from the enhanced double-layer charging and Faradaic pseudocapacity of MnO2. Moreover, the fabricated symmetrical supercapacitor also exhibits excellent cycling stability with 89.1% capacitance retention over 10000 cycles, as well as high energy densities in both aqueous and organic electrolyte (24 Wh kg(-1) and 33 W kg(-1), respectively). Compared with frequently used noble metals to enhance the electrochemical performance of MnO2, the utilization of low cost Co/C nanobeads is proven to be more efficient and thus showing great potential for commercial application.

WOS标题词Science & Technology ; Technology
类目[WOS]Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Science & Technology - Other Topics ; Materials Science
关键词[WOS]ELECTROCHEMICAL SUPERCAPACITORS ; ASYMMETRIC SUPERCAPACITORS ; NANOSTRUCTURED MNO2 ; MANGANESE-DIOXIDE ; NANOTUBE ARRAYS ; ENERGY-STORAGE ; THIN-FILMS ; GRAPHENE ; HYBRID ; NANOPARTICLES
收录类别SCI
语种英语
WOS记录号WOS:000373748200017
源URL[http://ir.sic.ac.cn/handle/331005/23026]  
专题上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文
作者单位1.Univ Regensburg, Inst Organ Chem, Univ Str 31, D-93053 Regensburg, Germany
2.Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
3.Peking Univ, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
4.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Zhi, Jian,Reiser, Oliver,Huang, Fuqiang. Hierarchical MnO2 Spheres Decorated by Carbon-Coated Cobalt Nanobeads: Low-Cost and High-Performance Electrode Materials for Supercapacitors[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(13):8452-8459.
APA Zhi, Jian,Reiser, Oliver,&Huang, Fuqiang.(2016).Hierarchical MnO2 Spheres Decorated by Carbon-Coated Cobalt Nanobeads: Low-Cost and High-Performance Electrode Materials for Supercapacitors.ACS APPLIED MATERIALS & INTERFACES,8(13),8452-8459.
MLA Zhi, Jian,et al."Hierarchical MnO2 Spheres Decorated by Carbon-Coated Cobalt Nanobeads: Low-Cost and High-Performance Electrode Materials for Supercapacitors".ACS APPLIED MATERIALS & INTERFACES 8.13(2016):8452-8459.

入库方式: OAI收割

来源:上海硅酸盐研究所

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