中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Flexible all solid state supercapacitor with high energy density employing black titania nanoparticles as a conductive agent

文献类型:期刊论文

作者Zhi, Jian1,2; Yang, Chongyin1,2; Lin, Tianquan1,2; Cui, Houlei1,2,3,4; Wang, Zhou1,2,3,4; Zhang, Hui1,2; Huang, Fuqiang1,2,3,4
刊名NANOSCALE
出版日期2016
卷号8期号:7页码:4054-4062
英文摘要

Increasing the electrical conductivity of pseudocapacitive materials without changing their morphology is an ideal structural solution to realize both high electrochemical performance and superior flexibility for an all solid state supercapacitor (ASSSC). Herein, we fabricate a flexible ASSSC device employing black titania (TiO2-x:N) decorated two-dimensional (2D) NiO nanosheets as the positive electrode and mesoporous graphene as the negative electrode. In this unique design, NiO nanosheets are used as pseudocapacitive materials and TiO2-x:N nanoparticles serve as the conductive agent. Owing to the excellent electrical conductivity of TiO2-x:N and well defined "particle on sheet" planar structure of NiO/TiO2-x:N composites, the 2D morphology of the decorated NiO nanosheets is completely retained, which efficiently reinforces the pseudocapacitive activity and flexibility of the whole all solid state device. The maximum specific capacitance of fabricated the NiO/TiO2-x:N//mesoporous graphene supercapacitor can reach 133 F g(-1), which is 2 and 4 times larger than the values of the NiO based ASSSC employing graphene and carbon black as the conductive agent, respectively. In addition, the optimized ASSSC displays intriguing performances with an energy density of 47 W h kg(-1) in a voltage region of 0-1.6 V, which is, to the best of our knowledge, the highest value for flexible ASSSC devices. The impressive results presented here may pave the way for promising applications of black titania in high energy density flexible storage systems.

WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
关键词[WOS]SENSITIZED SOLAR-CELLS ; HIGH-PERFORMANCE ; ELECTRODE MATERIALS ; ELECTROCHEMICAL CAPACITORS ; ASYMMETRIC SUPERCAPACITOR ; ACTIVATED CARBON ; NANOTUBE ARRAYS ; MNO2 NANOSHEETS ; 3D GRAPHENE ; OXIDE
收录类别SCI
语种英语
WOS记录号WOS:000370761700024
源URL[http://ir.sic.ac.cn/handle/331005/23216]  
专题上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
3.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
4.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Zhi, Jian,Yang, Chongyin,Lin, Tianquan,et al. Flexible all solid state supercapacitor with high energy density employing black titania nanoparticles as a conductive agent[J]. NANOSCALE,2016,8(7):4054-4062.
APA Zhi, Jian.,Yang, Chongyin.,Lin, Tianquan.,Cui, Houlei.,Wang, Zhou.,...&Huang, Fuqiang.(2016).Flexible all solid state supercapacitor with high energy density employing black titania nanoparticles as a conductive agent.NANOSCALE,8(7),4054-4062.
MLA Zhi, Jian,et al."Flexible all solid state supercapacitor with high energy density employing black titania nanoparticles as a conductive agent".NANOSCALE 8.7(2016):4054-4062.

入库方式: OAI收割

来源:上海硅酸盐研究所

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