Luminescence properties of Ag nanoclusters doped SiO2-PbF2 oxyfluoride glasses
文献类型:期刊论文
作者 | Zhou, Zhenzhen1; Liu, Guanghui1; Wei, Qinhua1,2; Yang, Hua1,2; Liu, Qian1 |
刊名 | JOURNAL OF LUMINESCENCE
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出版日期 | 2016 |
卷号 | 169页码:695-700 |
关键词 | Ag nanodusters Oxyfluoride glass Luminescence properties Fast decay time |
英文摘要 | Luminescent Ag nanoclusters doped solid host, such as glass, are very promising new materials for lighting applications due to their good mechanical and optical properties. In the present work, transparent Ag nanoclusters doped oxyfluoride amorphous glasses, having starting composition of 30SiO(2)-70PbF(2)-xAgNO(3) (x=0, 0.5, 3 mol%), were prepared using melt quenching technique. The Ag nanoclusters are spontaneously created during the casting of glass. The prepared Ag nanoclusters doped glasses emit green-yellow light under exposure to UV lamp (lambda(ex)=365 nm). The emission spectra of Ag nanoclusters doped glass show a red shift with the increase of excitation wavelength, and the excitation spectra show a similar red shift, that comes from Ag nanoclusters with different sizes and different local surroundings. The decay time of the Ag nanoclusters doped glass detected at the optimum wavelength (lambda(ex)=370 nm, lambda(ex) =530 nm) is only 2.1 ns, which may be attributed to the spin allowed singlet-singlet transitions of Ag-4(2+) tetramers. High temperature photoluminescence spectra of the glass (x=3) show a slight decrease in luminescence intensity with the increase of temperature, and the luminescence intensity at 80 degrees C is about 60% of that at 25 degrees C. The Ag nanoclusters were effectively protected and stabilized by the 30SiO(2)-70PbF(2) glass host. (C) 2015 Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Optics |
研究领域[WOS] | Optics |
关键词[WOS] | SILVER ; HOST ; IONS |
收录类别 | SCI ; ISTP |
语种 | 英语 |
WOS记录号 | WOS:000365606200058 |
源URL | [http://ir.sic.ac.cn/handle/331005/23352] ![]() |
专题 | 上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文 |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Zhenzhen,Liu, Guanghui,Wei, Qinhua,et al. Luminescence properties of Ag nanoclusters doped SiO2-PbF2 oxyfluoride glasses[J]. JOURNAL OF LUMINESCENCE,2016,169:695-700. |
APA | Zhou, Zhenzhen,Liu, Guanghui,Wei, Qinhua,Yang, Hua,&Liu, Qian.(2016).Luminescence properties of Ag nanoclusters doped SiO2-PbF2 oxyfluoride glasses.JOURNAL OF LUMINESCENCE,169,695-700. |
MLA | Zhou, Zhenzhen,et al."Luminescence properties of Ag nanoclusters doped SiO2-PbF2 oxyfluoride glasses".JOURNAL OF LUMINESCENCE 169(2016):695-700. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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