An intermediate phase (NH4)(2)V4O9 and its effects on the hydrothermal synthesis of VO2 (M) nanoparticles
文献类型：期刊论文
| 作者 | Dong, Bingrong1; Shen, Nan1; Cao, Chuanxiang1; Chen, Zhang2; Luo, Hongjie1,2; Gao, Yanfeng1,2 |
| 刊名 | CRYSTENGCOMM
 |
| 出版日期 | 2016 |
| 卷号 | 18期号:4页码:558-565 |
| 英文摘要 | The hydrothermal synthesis of VO2 (M) nanoparticles is commonly considered as a result of the transformation of intermediate phase VO2 (A) or VO2 (B). Here, we found a new intermediate phase (NH4)(2)V4O9 that appeared in the hydrothermal synthesis and played a crucial role in the formation of VO2 (M) nanoparticles. Then, the mechanism for the transformation of intermediate (NH4)(2)V4O9 to VO2 (M) was described as a self-assembly-decomposition-nucleation-growth process. Pure crystalline VO2 nanoparticles were ultimately obtained and showed excellent thermochromic properties. The phase-transition temperature T-c of VO2 (M) nanoparticles is approximately 65 degrees C. Furthermore, VO2 flexible foils on PET at a VO2 solid content of 1.5-2.0% show excellent optical properties with luminous transmittance (T-lum) > 50% and solar energy modulation ability (Delta T-sol) > 15%. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary ; Crystallography |
| 研究领域[WOS] | Chemistry ; Crystallography |
| 关键词[WOS] | VANADIUM DIOXIDE POWDERS ; OPTICAL-PROPERTIES ; THIN-FILMS ; THERMOCHROMIC PROPERTIES ; INSULATOR-TRANSITION ; MULTILAYER FILMS ; TRANSFORMATION ; TEMPERATURE ; PROPERTY ; TRANSMITTANCE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000368400400008 |
| 源URL | [http://ir.sic.ac.cn/handle/331005/23271]  |
| 专题 | 上海硅酸盐研究所_古陶瓷与工业陶瓷工程研究中心_期刊论文 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200444, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Bingrong,Shen, Nan,Cao, Chuanxiang,et al. An intermediate phase (NH4)(2)V4O9 and its effects on the hydrothermal synthesis of VO2 (M) nanoparticles[J]. CRYSTENGCOMM,2016,18(4):558-565. |
| APA | Dong, Bingrong,Shen, Nan,Cao, Chuanxiang,Chen, Zhang,Luo, Hongjie,&Gao, Yanfeng.(2016).An intermediate phase (NH4)(2)V4O9 and its effects on the hydrothermal synthesis of VO2 (M) nanoparticles.CRYSTENGCOMM,18(4),558-565. |
| MLA | Dong, Bingrong,et al."An intermediate phase (NH4)(2)V4O9 and its effects on the hydrothermal synthesis of VO2 (M) nanoparticles".CRYSTENGCOMM 18.4(2016):558-565. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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