CaAlSiN3:Eu2+ translucent ceramic: a promising robust and efficient red color converter for solid state laser displays and lighting
文献类型：期刊论文
| 作者 | Li, Shuxing1,2,3; Zhu, Qiangqiang2,4; Wang, Le5; Tang, Daiming6; Cho, Yujin2,7; Liu, Xuejian1; Hirosaki, Naoto2; Nishimura, Toshiyuki2; Sekiguchi, Takashi7; Huang, Zhengren1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY C
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:35页码:8197-8205 |
| 英文摘要 | As an excellent red phosphor, CaAlSiN3:Eu2+ plays a major role in high color rendition or wide color gamut white light-emitting diodes, but it can hardly be used in high-power laser displays and lighting due to the intrinsic low thermal performance of the phosphor/silicone resin mixture. To apply CaAlSiN3:Eu2+ in laser lighting devices, a bulk ceramic form is thus required to survive thermal attack and high flux density irradiation. However, it remains an unsolved great challenge to fabricate fully densified CaAlSiN3:Eu2+ ceramics. Here, for the first time, translucent CaAlSiN3:Eu2+ ceramics with an interesting composite microstructure, where red-emitting phosphor particles with a core-shell structure are uniformly embedded in a non-luminescent alpha-Sialon matrix, are successfully synthesized using Si3N4 and SiO2 as sintering additives. The luminescence ceramic is superior to the corresponding powder phosphor in terms of its enhanced thermal stability (15% increase) and thermal conductivity (4 W m(-1) K-1). It has a high external quantum efficiency of 60% (87% that of the powder) upon 450 nm excitation, and a luminous efficacy of 10.6 lm W-1 when irradiated under a blue laser flux density of 0.75 W mm(-2). The translucent CaAlSiN3:Eu2+ ceramic is thus supposed to be a potential color converter used in emerging laser lighting and display technologies. |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| 类目[WOS] | Materials Science, Multidisciplinary ; Physics, Applied |
| 研究领域[WOS] | Materials Science ; Physics |
| 关键词[WOS] | PROJECTION DISPLAYS ; YELLOW PHOSPHOR ; EMITTING-DIODES ; MGAL2O4 SPINEL ; ALPHA-SIALON ; WHITE LEDS ; SYSTEM ; MICROSTRUCTURE ; OPTIMIZATION ; LUMINESCENCE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000382834900007 |
| 源URL | [http://ir.sic.ac.cn/handle/331005/22846]  |
| 专题 | 上海硅酸盐研究所_结构陶瓷与复合材料工程研究中心_期刊论文 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Natl Inst Mat Sci, Sialon Grp, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China 5.China Jiliang Univ, Coll Opt & Elect Technol, Hangzhou 310018, Zhejiang, Peoples R China 6.Natl Inst Mat Sci, Thermal Energy Mat Grp, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan 7.Natl Inst Mat Sci, Nano Device Characterizat Grp, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan 8.Xiamen Univ, Coll Mat, Xiamen 361005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Shuxing,Zhu, Qiangqiang,Wang, Le,et al. CaAlSiN3:Eu2+ translucent ceramic: a promising robust and efficient red color converter for solid state laser displays and lighting[J]. JOURNAL OF MATERIALS CHEMISTRY C,2016,4(35):8197-8205. |
| APA | Li, Shuxing.,Zhu, Qiangqiang.,Wang, Le.,Tang, Daiming.,Cho, Yujin.,...&Xie, Rong-Jun.(2016).CaAlSiN3:Eu2+ translucent ceramic: a promising robust and efficient red color converter for solid state laser displays and lighting.JOURNAL OF MATERIALS CHEMISTRY C,4(35),8197-8205. |
| MLA | Li, Shuxing,et al."CaAlSiN3:Eu2+ translucent ceramic: a promising robust and efficient red color converter for solid state laser displays and lighting".JOURNAL OF MATERIALS CHEMISTRY C 4.35(2016):8197-8205. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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