中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups

文献类型:期刊论文

作者Ceng XH(曾祥华)1,2; Xu DQ(徐大乾)1; Miao CX(苗成霞)1; Xia CG(夏春谷)1; Sun W(孙伟)1
刊名RSC Advances
出版日期2014
卷号4期号:87页码:46494-46497
ISSN号2046-2069
通讯作者孙伟
英文摘要

An efficient method for synthesizing diaryl ketones via merging of oxidative cleavage of C–C double bonds and recombination of aromatic groups is developed with Et4NI (2.5 mol%) as the catalyst and NaIO4 as the oxidant. The control experiments provide valuable mechanistic insights into the formation of diaryl ketones, and suggest that NaIO4 serves as an epoxidation and nucleophilic deformylation reagent.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21103207)
语种英语
WOS记录号WOS:000342761800012
源URL[http://210.77.64.217/handle/362003/21324]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China
推荐引用方式
GB/T 7714
Ceng XH,Xu DQ,Miao CX,et al. Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups[J]. RSC Advances,2014,4(87):46494-46497.
APA Ceng XH,Xu DQ,Miao CX,Xia CG,&Sun W.(2014).Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups.RSC Advances,4(87),46494-46497.
MLA Ceng XH,et al."Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups".RSC Advances 4.87(2014):46494-46497.

入库方式: OAI收割

来源:兰州化学物理研究所

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