Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2
文献类型：期刊论文
| 作者 | Zhang, CF; Wang, X; Li, MR; Zhang, ZX; Wang, YH; Si, R; Wang, F |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2016 |
| 卷号 | 37期号:9页码:1569-1578 |
| 关键词 | MoS2 Coordinative unsaturated Mo Nitroarene Transfer hydrogenation Formate Heterogeneous catalysis |
| ISSN号 | 0253-9837 |
| 通讯作者 | Wang, F (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China. |
| 英文摘要 | We present an efficient approach for the chemoselective synthesis of arylamines from nitroarenes and formate over an oxygen-implanted MoS2 catalyst (O-MoS2). O-MoS2 was prepared by incomplete sulfidation and reduction of an ammonium molybdate precursor. A number of Mo-O bonds were implanted in the as-synthesized ultrathin O-MoS2 nanosheets. As a consequence of the different coordination geometries of O (MoS2) and S (MoS2), and lengths of the Mo-O and Mo-S bonds, the implanted Mo-O bonds induced obvious defects and more coordinatively unsaturated (CUS) Mo sites in O-MoS2, as confirmed by X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, high resolution transmission electron microscopy, and extended X-ray absorption fine structure characterization of various MoS2-based materials. O-MoS2 with abundant CUS Mo sites was found to efficiently catalyze the chemoselective reduction of nitroarenes to arylamines. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000384156400018 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/26446]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Zhang, CF,Wang, X,Li, MR,et al. Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(9):1569-1578. |
| APA | Zhang, CF.,Wang, X.,Li, MR.,Zhang, ZX.,Wang, YH.,...&Wang, F.(2016).Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2.CHINESE JOURNAL OF CATALYSIS,37(9),1569-1578. |
| MLA | Zhang, CF,et al."Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2".CHINESE JOURNAL OF CATALYSIS 37.9(2016):1569-1578. |
入库方式： OAI收割
来源：上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。