Cu-3(PO4)(2)/C composite as a high-capacity cathode material for rechargeable Na-ion batteries
文献类型：期刊论文
| 作者 | Zhao, WG; Zhong, GM; McDonald, MJ; Gong, ZL; Liu, R; Bai, JY; Yang, C; Li, SG; Zhao, WM; Wang, HC |
| 刊名 | NANO ENERGY
 |
| 出版日期 | 2016 |
| 卷号 | 27页码:420-429 |
| 关键词 | Conversion-type materials High capacity Cu-3(PO4)(2)/C Rechargeability Solid-state NMR XAFS techniques |
| ISSN号 | 2211-2855 |
| 通讯作者 | Yang, Y (reprint author), Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, Sch Energy Res, Xiamen 361005, Fujian, Peoples R China. ; Yang, Y (reprint author), Xiamen Univ, Dept Chem, Xiamen 361005, Fujian, Peoples R China. |
| 英文摘要 | Conversion-type materials are an appealing alternative to conventional intercalation compounds as cathode materials for sodium ion batteries, due to their high capacities. In this paper, we report for the first time that carbon-coated copper phosphate (Cu-3(PO4)(2)/C) can be used as a novel high-capacity cathode for rechargeable Na batteries. Cu-3(PO4)(2)/C shows a reversible capacity up to 290 mA h g(-1) at a current of 20 mA g land 190 mA h g(-1) at 400 mA g(-1), with capacity retention of 210 and 160 mA h g(-1) respectively after 30 cycles. The detailed sodium storage mechanisms were studied by employing ex-situ XRD, HR-TEM, solid-state NMR and XAFS techniques. The results clearly indicate that Cu-3(PO4)(2) can transform into Na3PO4 and Cu particles after discharge. Furthermore, Cu can react with Na3PO4 to form copper phosphate and NaxCuyPO4 in the charge process, determining the rechargeability of Cu-3(PO4)(2). (C) 2016 Elsevier Ltd. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000384910500046 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/26463]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Zhao, WG,Zhong, GM,McDonald, MJ,et al. Cu-3(PO4)(2)/C composite as a high-capacity cathode material for rechargeable Na-ion batteries[J]. NANO ENERGY,2016,27:420-429. |
| APA | Zhao, WG.,Zhong, GM.,McDonald, MJ.,Gong, ZL.,Liu, R.,...&Yang, Y.(2016).Cu-3(PO4)(2)/C composite as a high-capacity cathode material for rechargeable Na-ion batteries.NANO ENERGY,27,420-429. |
| MLA | Zhao, WG,et al."Cu-3(PO4)(2)/C composite as a high-capacity cathode material for rechargeable Na-ion batteries".NANO ENERGY 27(2016):420-429. |
入库方式： OAI收割
来源：上海应用物理研究所
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