Th(H2O)((IO3)-O-V)(2)[I-VII 0.6V1.76O7(OH)]: A Mixed-Valent Iodine Compound Containing Periodate Stabilized by Crystallographically Compatible Lattice Sites
文献类型：期刊论文
| 作者 | Wang, YX; Zhang, LJ; Chen, LH; Li, WF; Dai, X; Diwu, J; Wang, JQ; Chai, ZF; Wang, S |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2016 |
| 卷号 | 55期号:23页码:12101-12104 |
| ISSN号 | 0020-1669 |
| 通讯作者 | Wang, S (reprint author), Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd,Suzhou Ind Pk, Suzhou, Jiangsu, Peoples R China. ; Wang, S (reprint author), Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd,Suzhou Ind Pk, Suzhou, Jiangsu, Peoples R China. |
| 英文摘要 | Periodate is a strong oxidant and is often reduced to IO3- or I-2 under hydrothermal conditions. Here, we present a rare case of a mixed-valent iodate(V)/periodate (VII) compound, Th(H2O)((IO3)-O-v)(2)[I-VII (0.6) V1.76O7(OH)], prepared with a hydrothermal method starting from periodic acid. Crystallographic results demonstrate that heptavalent iodine adopts (IO6)-O-VII distorted octahedral geometries, which are stabilized on the crystallographically compatible crystal lattice sites of VO6 octahedra through an aliovalent substitutional disorder mechanism. X-ray photoelectron and synchrotron radiation X-ray absorption spectroscopes both quantitatively confirm the presence of mixed valent iodine oxo anions with a molar ratio (I-V/I-VII) of 4:1, consistent with the single crystal X-ray analysis. The crystallization of mixed-valent products with compatible lattice site can be fancily utilized for stabilizing the uncommon oxidation states of other elements in general. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000389497600001 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/26652]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Wang, YX,Zhang, LJ,Chen, LH,et al. Th(H2O)((IO3)-O-V)(2)[I-VII 0.6V1.76O7(OH)]: A Mixed-Valent Iodine Compound Containing Periodate Stabilized by Crystallographically Compatible Lattice Sites[J]. INORGANIC CHEMISTRY,2016,55(23):12101-12104. |
| APA | Wang, YX.,Zhang, LJ.,Chen, LH.,Li, WF.,Dai, X.,...&Wang, S.(2016).Th(H2O)((IO3)-O-V)(2)[I-VII 0.6V1.76O7(OH)]: A Mixed-Valent Iodine Compound Containing Periodate Stabilized by Crystallographically Compatible Lattice Sites.INORGANIC CHEMISTRY,55(23),12101-12104. |
| MLA | Wang, YX,et al."Th(H2O)((IO3)-O-V)(2)[I-VII 0.6V1.76O7(OH)]: A Mixed-Valent Iodine Compound Containing Periodate Stabilized by Crystallographically Compatible Lattice Sites".INORGANIC CHEMISTRY 55.23(2016):12101-12104. |
入库方式： OAI收割
来源：上海应用物理研究所
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