Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst
文献类型：期刊论文
| 作者 | Zhang, CF; Zhang, ZX; Wang, X; Li, MR; Lu, JM; Si, R; Wang, F |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2016 |
| 卷号 | 525页码:85-93 |
| 关键词 | MoS2 MoOx N2H4 Transfer hydrogenation Nitro reduction |
| ISSN号 | 0926-860X |
| 通讯作者 | Wang, F (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China. |
| 英文摘要 | We present an efficient approach for chemoselective synthesis of various functionalized arylamines from nitroarenes over an oxygen-implanted MoS2 catalyst (O-MoS2). The HRTEM, XRD, XPS, Raman, EXAFS and NH3-TPD characterizations show the existence of (MoOx)-O-Iv structure and abundant coordinative unsaturated (CUS) Mo sites in the 2D-layer structure of O-MoS2. In the transfer hydrogenation of nitroarenes with hydrazine hydrate, the (MoOx)-O-Iv structure works as the catalytic active center. The N2H4 selectively decomposes to the active hydrogen species in polar electronic states (H delta- and He delta+), which show high chemoselectivity toward the nitro reduction over C=C, C=C, and C N groups. The O-MoS2 catalyst can be recovered in a facile manner from the reaction mixture and recycled four times without any significant loss of activity. (C) 2016 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000383823200010 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/26666]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Zhang, CF,Zhang, ZX,Wang, X,et al. Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst[J]. APPLIED CATALYSIS A-GENERAL,2016,525:85-93. |
| APA | Zhang, CF.,Zhang, ZX.,Wang, X.,Li, MR.,Lu, JM.,...&Wang, F.(2016).Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst.APPLIED CATALYSIS A-GENERAL,525,85-93. |
| MLA | Zhang, CF,et al."Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst".APPLIED CATALYSIS A-GENERAL 525(2016):85-93. |
入库方式： OAI收割
来源：上海应用物理研究所
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