中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Catalytic conversion of substituted and un-substituted cyclohexanone into corresponding enones and phenols by nanocatalysts under acid or base-free reaction conditions

文献类型:期刊论文

作者Shah, Mazloom ; Zhang, Fan ; Ahmad, Ashfaq
刊名APPLIED CATALYSIS A-GENERAL
出版日期2017
卷号531期号:x页码:161-168
关键词Metallic and bimetallic nanoparticles Heterogeneous nanocatalysts Catalytic conversion Cyclic ketones Enones and phenols
中文摘要The catalytic conversion of substituted and unsubstituted cyclohexanones to the corresponding enones and aromatic alcohol catalyzed by Pd, Pd-1, Pd-cube, Cu, Ni, Ag@Pd and Ni-Sn nanocatalysts has been studied in the presence of O-2 as the oxidant without using any additives i.e. acid or base or ligand. The optimization of experimental parameters for dehydrogenation of cyclohexanones was established to achieve maximum yield of the product by using Pd nanocatalyst. The conversion of cyclohexanone, cyclohexenone, 3-methyl cyclohexanone and 3-methyl cyclohexenone catalyzed by Pd nanocatalyst at 80 degrees C, 10 atm O-2 pressure after 24 h, led to a 79%, 49%, 62% and 25% yields of desired products, respectively. Then, the conversion of substituted and unsubstituted cyclohexanones investigated in the presence of various nanocatalysts i.e., Pd-1, Pd-cube, Cu, Ni,Ag@Pd and Ni-Sn nanoparticles and was compared their percentage yields.
公开日期2017-03-01
源URL[http://ir.xtbg.org.cn/handle/353005/10296]  
专题西双版纳热带植物园_生物能源研究组
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GB/T 7714
Shah, Mazloom,Zhang, Fan,Ahmad, Ashfaq. Catalytic conversion of substituted and un-substituted cyclohexanone into corresponding enones and phenols by nanocatalysts under acid or base-free reaction conditions[J]. APPLIED CATALYSIS A-GENERAL,2017,531(x):161-168.
APA Shah, Mazloom,Zhang, Fan,&Ahmad, Ashfaq.(2017).Catalytic conversion of substituted and un-substituted cyclohexanone into corresponding enones and phenols by nanocatalysts under acid or base-free reaction conditions.APPLIED CATALYSIS A-GENERAL,531(x),161-168.
MLA Shah, Mazloom,et al."Catalytic conversion of substituted and un-substituted cyclohexanone into corresponding enones and phenols by nanocatalysts under acid or base-free reaction conditions".APPLIED CATALYSIS A-GENERAL 531.x(2017):161-168.

入库方式: OAI收割

来源:西双版纳热带植物园

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