Uniformly dispersed carbon-supported bimetallic ruthenium-platinum electrocatalysts for the methanol oxidation reaction
文献类型:期刊论文
作者 | Zheng, Yuying1; Zhan, Hengtong1; Fang, Yanxiong1; Zeng, Jianhuang2; Liu, Hui3; Yang, Jun3; Liao, Shijun2 |
刊名 | JOURNAL OF MATERIALS SCIENCE
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出版日期 | 2017-03-01 |
卷号 | 52期号:6页码:3457-3466 |
ISSN号 | 0022-2461 |
DOI | 10.1007/s10853-016-0635-8 |
文献子类 | Article |
英文摘要 | Reducing the Pt-based electrocatalysts to sub-nanometer sizes is an effective way to achieve high utilization of noble metals. Herein, we report a successive route to synthesize carbon-supported bimetallic ruthenium-platinum electrocatalysts (Ru-Pt/C) with uniform dispersion and fine sizes. In this strategy, carbon-supported Ru nanoparticles (Ru/C) with a mean size of 1.4 nm are firstly prepared in a mixture of ethylene glycol and water, and the Pt precursors are then reduced in the presence of pre-formed Ru/C. The average diameter of the bimetallic Ru-Pt particles on carbon supports is 1.9 nm, which corresponds to one to two Pt layers deposited on the surface of Ru seeds. The as-prepared bimetallic Ru-Pt/C electrocatalysts are analyzed by the CO stripping voltammetry, a diagnostic electrochemical tool. Compared with the commercial PtRu/C catalyst and the control PtRu/C prepared by a conventional co-reduction method, the bimetallic Ru-Pt/C has higher electrochemical surface area (92.5 m(2) g(-1)) and mass activity (483 A g(-1)) for methanol oxidation reaction. The strategy reported in this study is effective to produce fine bimetallic Ru-Pt particles (less than 2.0 nm) with uniform dispersion and high activity. |
WOS关键词 | Oxygen-reduction Reaction ; Core-shell Nanoparticles ; Electrochemical Deposition Method ; Fuel-cells ; High-performance ; Catalyst ; Electrooxidation ; Tolerance ; Ultrathin ; Electrode |
WOS研究方向 | Materials Science |
语种 | 英语 |
WOS记录号 | WOS:000390125500042 |
资助机构 | Key Project on the National Natural Science Foundation-Guangdong Joint Foundation(U1301245) ; National Natural Science Foundation of China(51572090 ; Natural Science Foundation of Guangdong Province(2016A030313484) ; Science and Technology Planning Project of Guangdong Province(2014A010105041 ; 21376247 ; 2016A010103028) ; 21506225 ; 21573240) |
源URL | [http://ir.ipe.ac.cn/handle/122111/21865] ![]() |
专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
作者单位 | 1.Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China 2.South China Univ Technol, Sch Chem & Chem Engn, Guangdong Key Lab Fuel Cell Technol, Guangzhou 510641, Guangdong, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, Yuying,Zhan, Hengtong,Fang, Yanxiong,et al. Uniformly dispersed carbon-supported bimetallic ruthenium-platinum electrocatalysts for the methanol oxidation reaction[J]. JOURNAL OF MATERIALS SCIENCE,2017,52(6):3457-3466. |
APA | Zheng, Yuying.,Zhan, Hengtong.,Fang, Yanxiong.,Zeng, Jianhuang.,Liu, Hui.,...&Liao, Shijun.(2017).Uniformly dispersed carbon-supported bimetallic ruthenium-platinum electrocatalysts for the methanol oxidation reaction.JOURNAL OF MATERIALS SCIENCE,52(6),3457-3466. |
MLA | Zheng, Yuying,et al."Uniformly dispersed carbon-supported bimetallic ruthenium-platinum electrocatalysts for the methanol oxidation reaction".JOURNAL OF MATERIALS SCIENCE 52.6(2017):3457-3466. |
入库方式: OAI收割
来源:过程工程研究所
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