Monodisperse Pt nanoparticles anchored on N-doped black TiO2 as high performance bifunctional electrocatalyst
文献类型：期刊论文
| 作者 | Wang, Xin1,2; Yuan, Xiaotao1,2; Liu, Xiangye1,2; Dong, Wujie1,2; Dong, Chenlong1,2; Lou, Minghe1,2; Li, Juncen1,2; Lin, Tianquan3; Huang, Fuqiang1,2,3 |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2017-04-15 |
| 卷号 | 701页码:669-675 |
| 关键词 | Nitrogen-doped black titania Oxygen reduction reaction Hydrogen evolution reaction Durability Methanol tolerance |
| 英文摘要 | Nitrogen-doped black TiO2 (Nx:TiO2-x) recently attracted attention as a novel photocatalyst. It has higher electrical conductivity and more suitable energy level for oxygen reduction and hydrogen evolution than pure TiO2 due to the presence of Ti3+ species. The unique electronic structure and strong metal-support interaction make it a candidate support for Pt-based electrocatalyst. Carbon is universal as support of Pt based electrocatalyst. However, it is restricted to the poor durability and bad methanol tolerance. On the contrary, the chemical stability of nitrogen-doped TiO2 contributes to the higher durability and methanol tolerance of Pt/Nx:TiO2, than Pt/C catalyst. Monodisperse Pt nanoparticles are loaded on Nx:TiO2-x by a facile borohydride reduction method. The Pt/Nx:TiO2-x hybrid shows better oxygen reduction reaction (ORR) activity with the half wave potential of 0.78 V (vs. reversible hydrogen electrode) than Pt and good hydrogen evolution reaction (HER) performance with 19 mV onset overpotential, similar to Pt/C catalyst. More importantly, Pt/Nx:TiO2-x catalyst has robust durability and higher methanol tolerance than Pt/C catalyst. All these electrostatic performances stem from the suitable energy level for ORR and HER and the strong interaction between Pt and Nx:TiO2-x support. This hybrid material is a promising candidate for the fuel cell in the future. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| 研究领域[WOS] | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 关键词[WOS] | SUPPORTED-PLATINUM CATALYST ; SENSITIZED SOLAR-CELLS ; METHANOL FUEL-CELLS ; CATHODE CATALYST ; PT/C CATALYSTS ; ACIDIC MEDIA ; OXIDATION ; NANOTUBES ; ELECTROOXIDATION ; OXIDE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000395839100083 |
| 源URL | [http://ir.sic.ac.cn/handle/331005/23572]  |
| 专题 | 上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文 |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Natl Lab, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xin,Yuan, Xiaotao,Liu, Xiangye,et al. Monodisperse Pt nanoparticles anchored on N-doped black TiO2 as high performance bifunctional electrocatalyst[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2017,701:669-675. |
| APA | Wang, Xin.,Yuan, Xiaotao.,Liu, Xiangye.,Dong, Wujie.,Dong, Chenlong.,...&Huang, Fuqiang.(2017).Monodisperse Pt nanoparticles anchored on N-doped black TiO2 as high performance bifunctional electrocatalyst.JOURNAL OF ALLOYS AND COMPOUNDS,701,669-675. |
| MLA | Wang, Xin,et al."Monodisperse Pt nanoparticles anchored on N-doped black TiO2 as high performance bifunctional electrocatalyst".JOURNAL OF ALLOYS AND COMPOUNDS 701(2017):669-675. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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