Heterogeneity in optimized solid-state synthesis of metavanadate AVO(3) (A = Rb, Cs)
文献类型：期刊论文
| 作者 | Sun, Guangyao1; Li, Wenjing1; Ji, Shidong1; Cao, Xun1,2; Jin, Ping1,3 |
| 刊名 | RESEARCH ON CHEMICAL INTERMEDIATES
 |
| 出版日期 | 2017 |
| 卷号 | 43期号:1页码:341-352 |
| 关键词 | AVO(3) Heterogeneity Methanol Optimized solid-state synthesis Oriented growth Defect |
| 英文摘要 | Methanol was used to optimize the solid-state synthesizing method of alkali metavanadates AVO(3) (A = Rb, Cs) for the first time and the benefits are discussed. Due to the optimization, four kinds of heterogeneous AVO(3) compounds, white CsVO3 [CsVO3 (W)], yellow CsVO3 [CsVO3 (Y)], white RbVO3 [RbVO3 (W)], and red RbVO3 [RbVO3 (R)], could be easily obtained. The colored compounds CsVO3 (Y) and RbVO3 (R) are reported for the first time and their synthetic process has been summarized, while their crystal structure, morphology, vibration spectroscopy, photoluminescence, moisture adsorption and thermodynamic properties were measured and compared to white compounds. The differences in properties of CsVO3 (Y) and RbVO3 (R) were hypothesized as the oriented growth and induced defects. All four AVO(3) compounds were excellent white-light-emitting phosphors, and CsVO3 (Y) and RbVO3 (R), with additional waterproofness, suggested much more practical value. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | LUMINESCENT PROPERTIES ; VANADATE GARNETS ; PHOSPHOR |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000393595100024 |
| 源URL | [http://ir.sic.ac.cn/handle/331005/23464]  |
| 专题 | 上海硅酸盐研究所_古陶瓷与工业陶瓷工程研究中心_期刊论文 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Dingxi 1295, Shanghai 200050, Peoples R China 2.Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA 3.Natl Inst Adv Ind Sci & Technol, Mat Res Inst Sustainable Dev, Nagoya, Aichi 4638560, Japan |
| 推荐引用方式 GB/T 7714 | Sun, Guangyao,Li, Wenjing,Ji, Shidong,et al. Heterogeneity in optimized solid-state synthesis of metavanadate AVO(3) (A = Rb, Cs)[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2017,43(1):341-352. |
| APA | Sun, Guangyao,Li, Wenjing,Ji, Shidong,Cao, Xun,&Jin, Ping.(2017).Heterogeneity in optimized solid-state synthesis of metavanadate AVO(3) (A = Rb, Cs).RESEARCH ON CHEMICAL INTERMEDIATES,43(1),341-352. |
| MLA | Sun, Guangyao,et al."Heterogeneity in optimized solid-state synthesis of metavanadate AVO(3) (A = Rb, Cs)".RESEARCH ON CHEMICAL INTERMEDIATES 43.1(2017):341-352. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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