Synthesis of Layered Rare-Earth Hydroxide Intercalated with Benzoate Ions
文献类型:期刊论文
作者 | Zhang, Lin1; Jiang, Danyu2; Zhang, Na3; Xia, Jinfeng2; Li, Qiang1 |
刊名 | SCIENCE OF ADVANCED MATERIALS
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出版日期 | 2017-03-01 |
卷号 | 9期号:3-4页码:452-455 |
关键词 | Nanosheets Atomic Force Microscopy Layered Compound Luminescence Rare-Earth |
英文摘要 | We report a new family of lanthanide-based inorganic-organic hybrid frameworks Y1.9Eu0.1(OH)(5)[C6H5COO] center dot 2H(2)O synthesized by homogeneous precipitation. The crystal structure obtained from powder X-ray diffraction data revealed that this material comprises two-dimensional cationic lanthanide hydroxide {[Ln(2)(OH)(5)(H2O)](+)}(infinity) layers, which are cross-linked by benzoate ligands into a three-dimensional pillared framework. The single layered nanosheets were obtained in n-butanol after the supersonic treatment. The morphologies of the nanosheets were a hexagonal structure about 800 nm in size as determined by transmission electron microscopy, and the thickness of the nanosheets was about 1.8 nm measured by atomic force microscopy. The fluorescence intensity of the D-5(0)-F-7(2) transition increased nearly 3.8 times. The lifetime of the material increased to 0.43 ms compared with the lifetime of Eu3+ in an aqueous medium of 0.1 ms. |
WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
类目[WOS] | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
研究领域[WOS] | Science & Technology - Other Topics ; Materials Science ; Physics |
关键词[WOS] | LUMINESCENCE PROPERTIES ; NANOSHEETS ; POWDERS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000397862500026 |
源URL | [http://ir.sic.ac.cn/handle/331005/23675] ![]() |
专题 | 上海硅酸盐研究所_无机材料分析测试中心_期刊论文 |
作者单位 | 1.East China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China 3.Shanghai Inst Technol, Dept Mat Engn, Shanghai 200235, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Lin,Jiang, Danyu,Zhang, Na,et al. Synthesis of Layered Rare-Earth Hydroxide Intercalated with Benzoate Ions[J]. SCIENCE OF ADVANCED MATERIALS,2017,9(3-4):452-455. |
APA | Zhang, Lin,Jiang, Danyu,Zhang, Na,Xia, Jinfeng,&Li, Qiang.(2017).Synthesis of Layered Rare-Earth Hydroxide Intercalated with Benzoate Ions.SCIENCE OF ADVANCED MATERIALS,9(3-4),452-455. |
MLA | Zhang, Lin,et al."Synthesis of Layered Rare-Earth Hydroxide Intercalated with Benzoate Ions".SCIENCE OF ADVANCED MATERIALS 9.3-4(2017):452-455. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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