中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of Layered Rare-Earth Hydroxide Intercalated with Benzoate Ions

文献类型:期刊论文

作者Zhang, Lin1; Jiang, Danyu2; Zhang, Na3; Xia, Jinfeng2; Li, Qiang1
刊名SCIENCE OF ADVANCED MATERIALS
出版日期2017-03-01
卷号9期号:3-4页码:452-455
关键词Nanosheets Atomic Force Microscopy Layered Compound Luminescence Rare-Earth
英文摘要We report a new family of lanthanide-based inorganic-organic hybrid frameworks Y1.9Eu0.1(OH)(5)[C6H5COO] center dot 2H(2)O synthesized by homogeneous precipitation. The crystal structure obtained from powder X-ray diffraction data revealed that this material comprises two-dimensional cationic lanthanide hydroxide {[Ln(2)(OH)(5)(H2O)](+)}(infinity) layers, which are cross-linked by benzoate ligands into a three-dimensional pillared framework. The single layered nanosheets were obtained in n-butanol after the supersonic treatment. The morphologies of the nanosheets were a hexagonal structure about 800 nm in size as determined by transmission electron microscopy, and the thickness of the nanosheets was about 1.8 nm measured by atomic force microscopy. The fluorescence intensity of the D-5(0)-F-7(2) transition increased nearly 3.8 times. The lifetime of the material increased to 0.43 ms compared with the lifetime of Eu3+ in an aqueous medium of 0.1 ms.
WOS标题词Science & Technology ; Technology ; Physical Sciences
类目[WOS]Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
研究领域[WOS]Science & Technology - Other Topics ; Materials Science ; Physics
关键词[WOS]LUMINESCENCE PROPERTIES ; NANOSHEETS ; POWDERS
收录类别SCI
语种英语
WOS记录号WOS:000397862500026
源URL[http://ir.sic.ac.cn/handle/331005/23675]  
专题上海硅酸盐研究所_无机材料分析测试中心_期刊论文
作者单位1.East China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
3.Shanghai Inst Technol, Dept Mat Engn, Shanghai 200235, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Lin,Jiang, Danyu,Zhang, Na,et al. Synthesis of Layered Rare-Earth Hydroxide Intercalated with Benzoate Ions[J]. SCIENCE OF ADVANCED MATERIALS,2017,9(3-4):452-455.
APA Zhang, Lin,Jiang, Danyu,Zhang, Na,Xia, Jinfeng,&Li, Qiang.(2017).Synthesis of Layered Rare-Earth Hydroxide Intercalated with Benzoate Ions.SCIENCE OF ADVANCED MATERIALS,9(3-4),452-455.
MLA Zhang, Lin,et al."Synthesis of Layered Rare-Earth Hydroxide Intercalated with Benzoate Ions".SCIENCE OF ADVANCED MATERIALS 9.3-4(2017):452-455.

入库方式: OAI收割

来源:上海硅酸盐研究所

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