Water Splitting for High-Yield Hydrogen Production Energized by Biomass Xylooligosaccharides Catalyzed by an Enzyme Cocktail
文献类型：期刊论文
| 作者 | Moustafa, Hanan M. A.1,2; Kim, Eui-Jin1; Zhu, Zhiguang3; Wu, Chang-Hao4; Zaghloul, Taha I.2; Adams, Michael W. W.4; Zhang, Y. -H. Percival1,3,5 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2016-09-21 |
| 卷号 | 8期号:18页码:2898-2902 |
| 关键词 | biocatalysis enzymes hydrogen oligosaccharides water splitting |
| 英文摘要 | Green hydrogen production through water splitting at low temperatures is highly desired for hydrogen economy. Herein, we demonstrate an in vitro non-natural enzymatic pathway to utilize the chemical energy stored in xylooligosaccharides from biomass to split water to produce a nearly theoretical yield of H-2 (i.e., approximate to 9.5 H-2 per xylose plus water). This pathway was constructed on the basis of the novel activities of phosphopentomutase catalyzing the conversion of D-xylose 1-phosphate into d-xylose 5-phosphate and of ribose 5-phosphate isomerase catalyzing the conversions of d-xylose 5-phosphate and D-xylulose 5-phosphate. This study suggests that the discovery of novel promiscuous enzyme activities is important to implement complicated biotransformations catalyzed by synthetic enzymatic pathways. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | THERMOTOGA-MARITIMA ; D-XYLOSE ; PURIFICATION ; ISOMERASE ; PHOSPHOPENTOMUTASE ; PROMISCUITY ; PATHWAY ; CASCADE ; GLUCOSE ; PROTEIN |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000386919300007 |
| 源URL | [http://124.16.173.210/handle/834782/2944]  |
| 专题 | 天津工业生物技术研究所_体外合成生物学研究组 张以恒_期刊论文 |
| 作者单位 | 1.Virginia Tech, Dept Biol Syst Engn, 304 Seitz Hall, Blacksburg, VA 24061 USA 2.Univ Alexandria, Dept Biotechnol, Inst Grad Studies & Res, 163 El Horreya Ave, Alexandria 21526, Egypt 3.Cell Free Bioinnovat Inc, 1800 Kraft Dr,Suite 222, Blacksburg, VA 24060 USA 4.Univ Georgia, Dept Biochem & Mol Biol, Athens, GA 30602 USA 5.Chinese Acad Sci, Tianjin Inst Ind Biotechnol, Tianjin Airport Econ Area, 32 West 7th Ave, Tianjin 300308, Peoples R China |
| 推荐引用方式 GB/T 7714 | Moustafa, Hanan M. A.,Kim, Eui-Jin,Zhu, Zhiguang,et al. Water Splitting for High-Yield Hydrogen Production Energized by Biomass Xylooligosaccharides Catalyzed by an Enzyme Cocktail[J]. CHEMCATCHEM,2016,8(18):2898-2902. |
| APA | Moustafa, Hanan M. A..,Kim, Eui-Jin.,Zhu, Zhiguang.,Wu, Chang-Hao.,Zaghloul, Taha I..,...&Zhang, Y. -H. Percival.(2016).Water Splitting for High-Yield Hydrogen Production Energized by Biomass Xylooligosaccharides Catalyzed by an Enzyme Cocktail.CHEMCATCHEM,8(18),2898-2902. |
| MLA | Moustafa, Hanan M. A.,et al."Water Splitting for High-Yield Hydrogen Production Energized by Biomass Xylooligosaccharides Catalyzed by an Enzyme Cocktail".CHEMCATCHEM 8.18(2016):2898-2902. |
入库方式： OAI收割
来源：天津工业生物技术研究所
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