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Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling
文献类型：期刊论文
| 作者 | Wang, Pan1; Tang, Shan1; Huang, Pengfei1; Lei AW(雷爱文)1,2 |
| 刊名 | Angewandte Chemie International Edition
 |
| 出版日期 | 2017 |
| 卷号 | 56期号:11页码:3009-3013 |
| 关键词 | C-H functionalization C-S bond formation dehydrogenation electrochemistry radical cations |
| ISSN号 | 1433-7851 |
| 通讯作者 | 雷爱文 |
| 英文摘要 | An environmentally friendly electrocatalytic protocol has been developed for dehydrogenative C-H/S-H crosscoupling. This method enabled C-S bond formation under catalyst-and oxidant-free conditions. Under undivided electrolysis conditions, various aryl/heteroaryl thiols and electronrich arenes afforded the C-S bond-formation products in 24-99% yield. A preliminary mechanistic study indicated that the generation of aryl radical cation intermediates is key to the success of this transformation. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (21390402;21520102003);the Ministry of Science and Technology of China (2012YQ120060);the Fundamental Research Funds for the Central Universities;the Program of Introducing Talents of Discipline to Universities of China (111 Program) |
| 语种 | 英语 |
| WOS记录号 | WOS:000397307600033 |
| 源URL | [http://210.77.64.217/handle/362003/21644]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Pan,Tang, Shan,Huang, Pengfei,et al. Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling[J]. Angewandte Chemie International Edition,2017,56(11):3009-3013. |
| APA | Wang, Pan,Tang, Shan,Huang, Pengfei,&Lei AW.(2017).Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling.Angewandte Chemie International Edition,56(11),3009-3013. |
| MLA | Wang, Pan,et al."Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling".Angewandte Chemie International Edition 56.11(2017):3009-3013. |
入库方式： OAI收割
来源：兰州化学物理研究所
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