中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Characterization of oil shale pyrolysis by solid heat carrier in moving bed with internals

文献类型:期刊论文

作者Lai, Dengguo1,2; Zhang, Guangyi1; Xu, Guangwen1,3
刊名FUEL PROCESSING TECHNOLOGY
出版日期2017-04-01
卷号158页码:191-198
关键词Pyrolysis Oil Shale Internals Steam Atmosphere Shale Ash Ceramic Balls
ISSN号0378-3820
DOI10.1016/j.fuproc.2017.01.005
文献子类Article
英文摘要

Oil shale pyrolysis by solid heat carrier in moving bed with internals (MBI) was investigated with the aim to identify the effect of oil shale properties (moisture content and particle size) and heat carrier types on the physicochemical properties and distributions of pyrolysis products. Pyrolysis of oil shale with high moisture content of 10 wt% caused obvious increase in shale oil yield due to the protective effect of steam atmosphere by its reducing secondary reactions and also catalysis action of shale ash. The obtained highest shale oil yield was close to the yield of Fischer Assay. Pyrolyzing dried oil shale produced shale oil containing more light oils (gasoline and diesel) and allowed higher gas yield. Pyrolysis of large size (i.e. >10 mm) oil shale reduced oil yield but increased light oil content due to the required long time for heat transfer and intra-patticle volatile diffusion. Comparing with ceramic balls, shale ash as the heat carrier presented a favorably catalytic effect on cracking and upgrading of shale oil. With increasing pyrolysis temperature from 465 to 525 degrees C, using shale ash greatly raised light oil content by 10.24% (relatively), considerably reduced the content of heteroatomic compounds, and promoted the conversion of aliphatics to aromatics. Shale ash carrier particles enabled better dust removal than ceramic balls did to attain oil product with a dust content below 0.2 wt%. Generally, oil shale pyrolysis using shale ash heat carrier in MBI process has obvious effects of in-situ shale oil upgrading and in-bed dust removal to allow good pyrolysis performance. (C) 2017 Elsevier B.V. All rights reserved.

WOS关键词Fixed-bed ; Steam ; Filtration ; Gas ; Temperature ; Technology ; Products ; Cracking ; Coking ; Filter
WOS研究方向Chemistry ; Energy & Fuels ; Engineering
语种英语
WOS记录号WOS:000394067000020
资助机构National Basic Research Program of China(2014CB744305)
源URL[http://ir.ipe.ac.cn/handle/122111/22012]  
专题过程工程研究所_多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chem Ind Corp Ltd, Southwest Res & Design Inst, Sichuan 610225, Peoples R China
推荐引用方式
GB/T 7714
Lai, Dengguo,Zhang, Guangyi,Xu, Guangwen. Characterization of oil shale pyrolysis by solid heat carrier in moving bed with internals[J]. FUEL PROCESSING TECHNOLOGY,2017,158:191-198.
APA Lai, Dengguo,Zhang, Guangyi,&Xu, Guangwen.(2017).Characterization of oil shale pyrolysis by solid heat carrier in moving bed with internals.FUEL PROCESSING TECHNOLOGY,158,191-198.
MLA Lai, Dengguo,et al."Characterization of oil shale pyrolysis by solid heat carrier in moving bed with internals".FUEL PROCESSING TECHNOLOGY 158(2017):191-198.

入库方式: OAI收割

来源:过程工程研究所

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