Deep hydrodenitrification of pyridine by solid catalyst coupling with ionic liquids under mild conditions
文献类型：期刊论文
| 作者 | Yao, Haoyu1,2; Wang, Gang1,2; Zuo, Cuncun2; Li, Chunshan1,2; Wang, Erqiang1; Zhang, Suojiang2 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2017-04-07 |
| 卷号 | 19期号:7页码:1692-1700 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c6gc03432b |
| 文献子类 | Article |
| 英文摘要 | A new route for deep hydrodenitrification (HDN) by solid catalyst coupling with ionic liquids (ILs) under mild conditions was proposed. Ni2P/SBA-15 activated at different temperatures were characterized with XRD, XPS, TG/DTA, and TEM and studied for further improvement. The deep HDN catalyzed by Ni2P/SBA-15 coupling with different ILs was evaluated. [Bmim] BF4 was selected as the best one compared with [Emim]BF4, [Bmim]Cl and [Bmim]Br. The effect of reaction temperature, hydrogen pressure and the amount of IL on denitrification efficiency was investigated with parallel experiments using Ni2P/SBA-15 coupling with [Bmim]BF4. The N-removal efficiency increased from 27.09% to 73.48% after optimization. The IL system could be recycled for three times without a significant decrease in HDN activity. The coupled catalyzed HDN process and mechanism were also proposed and evaluated preliminarily through molecular simulation. |
| WOS关键词 | Nitrogen-compounds ; Gas Oil ; Extractive Desulfurization ; Removal ; Hydrodesulfurization ; Hydrogenation ; Temperature ; Fuels ; 4,6-dimethyldibenzothiophene ; Denitrogenation |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000398146000017 |
| 资助机构 | National Science Fund for Excellent Young Scholars(21422607) ; National Natural Science Funds(21576261) ; National Basic Research Program of China (973 Program)(2015CB251401) ; Innovation Fund of Petro-China(2015D-5006-0406) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/22093]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 2.Univ Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Haoyu,Wang, Gang,Zuo, Cuncun,et al. Deep hydrodenitrification of pyridine by solid catalyst coupling with ionic liquids under mild conditions[J]. GREEN CHEMISTRY,2017,19(7):1692-1700. |
| APA | Yao, Haoyu,Wang, Gang,Zuo, Cuncun,Li, Chunshan,Wang, Erqiang,&Zhang, Suojiang.(2017).Deep hydrodenitrification of pyridine by solid catalyst coupling with ionic liquids under mild conditions.GREEN CHEMISTRY,19(7),1692-1700. |
| MLA | Yao, Haoyu,et al."Deep hydrodenitrification of pyridine by solid catalyst coupling with ionic liquids under mild conditions".GREEN CHEMISTRY 19.7(2017):1692-1700. |
入库方式： OAI收割
来源：过程工程研究所
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