Microwave-assisted synthesis of hierarchical mesoporous nano-Ti0(2)/cellulose composites for rapid adsorption of Pb2+
文献类型:期刊论文
作者 | Zhang, Jinju1,2,3; Li, Lei1,2; Li, Yanxiang1,2; Yang, Chuanfang1,2 |
刊名 | CHEMICAL ENGINEERING JOURNAL
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出版日期 | 2017-04-01 |
卷号 | 313页码:1132-1141 |
关键词 | Cellulose Mesoporous nano-TiO2 Microwave-irradiation Hierarchical structured composite Lead adsorption |
ISSN号 | 1385-8947 |
英文摘要 | Cellulose fibers were used as substrates to induce the formation of nano-Ti0(2) via heterogeneous titanium oxysulfate hydrolysis under microwave irradiation. The microwave provided fast heating for the one-pot reaction at 90 degrees C and contributed to the generation of 10 nm anatase TiO2 nanoparticles. These spherical particles further fused into 100 nm raspberry-like mesoporous TiO2 agglomerates uniformly distributed on the cellulose surface. The composite material was able to adsorb Pb2+ very rapidly from simulated wastewater with a maximum capacity of 42.5 mg/g. The adsorption, characterized by pseudo-second order kinetics and Freundlich isotherm, was attributed to the reaction between the hydroxyl groups of TiO2 and Pb2+ to form Pb-0 bond, as indicated by XPS analysis. The adsorbent can be easily regenerated for a number of times without significant reduction in adsorption performances. (C) 2016 Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Technology |
类目[WOS] | Engineering, Environmental ; Engineering, Chemical |
研究领域[WOS] | Engineering |
关键词[WOS] | HEAVY-METAL REMOVAL ; TITANIUM-DIOXIDE ; WASTE-WATER ; IN-SITU ; THERMOGRAVIMETRIC ANALYSIS ; TIO2 NANOCRYSTALS ; CELLULOSE FIBERS ; FACILE SYNTHESIS ; HYDROXYL GROUP ; COTTON FIBERS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000394723200114 |
源URL | [http://ir.ipe.ac.cn/handle/122111/22097] ![]() |
专题 | 过程工程研究所_生化工程国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Jinju,Li, Lei,Li, Yanxiang,et al. Microwave-assisted synthesis of hierarchical mesoporous nano-Ti0(2)/cellulose composites for rapid adsorption of Pb2+[J]. CHEMICAL ENGINEERING JOURNAL,2017,313:1132-1141. |
APA | Zhang, Jinju,Li, Lei,Li, Yanxiang,&Yang, Chuanfang.(2017).Microwave-assisted synthesis of hierarchical mesoporous nano-Ti0(2)/cellulose composites for rapid adsorption of Pb2+.CHEMICAL ENGINEERING JOURNAL,313,1132-1141. |
MLA | Zhang, Jinju,et al."Microwave-assisted synthesis of hierarchical mesoporous nano-Ti0(2)/cellulose composites for rapid adsorption of Pb2+".CHEMICAL ENGINEERING JOURNAL 313(2017):1132-1141. |
入库方式: OAI收割
来源:过程工程研究所
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