High-resolution and broadband mid-infrared Zeeman spectrum of gas-phase nitric oxide using a quantum cascade laser around 5.2 mu m
文献类型：期刊论文
| 作者 | Wu, Kuijun; Liu, Linmei; Chen, Zhenwei; Cheng, Xuewu; Yang, Yong; Li, Faquan |
| 刊名 | JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
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| 出版日期 | 2017-02-14 |
| 卷号 | 50期号:3 |
| 关键词 | Zeeman spectrum Lande g-factor Hund's coupling case laser spectroscopy |
| 英文摘要 | A broadly tunable single-mode quantum cascade laser operating around 5.2 mu m has been used to study the high-resolution and broadband mid-IR Zeeman spectrum of Gas-phase (NO)-N-14-O-16. The Zeeman spectrum signals in the R (from R-0.5 to R-22.5), Q (from Q(0.5) to Q(6.5)) and P (from P-1.5 to P-14.5) branches of the fundamental vibrational transition, X-2 Pi(1/2), X-2 Pi(3/2) (v= 1 0), have been recorded with both large spectral region (over the range of 1824-1947 cm(-1)) and high spectral resolution (< 0.001 cm(-1)) for the first time. We simulated the patterns of magnetic Zeeman split lines in the R, Q, and P branches, and calculated the Land g-factor gJ of the (2)Pi(1/2), (2)Pi(3/2) components for pure Hund's coupling case (a) and (b), and intermediate coupling (a-b) case. The experimental Zeeman spectrum measured at various values of magnetic field strength (from 0.04 to 0.32 T) at conditions of both B perpendicular to E and B parallel to E was calibrated by a 101.6mm long solid germanium etalon with a free spectral range (FSR) of 0.012 cm(-1). Good agreement between the calculated Lande g-factors using Radford's theory and their best fit values inferred from the experimental data was obtained, which suggests that the Lande g-factor in Hund's coupling case (a-b) is a better approximation, either at higher rotational quantum numbers, or at lower rotational levels, for both (2)Pi(1/2), (2)Pi(3/2) subsystems. Our results provide a more general evidence to determine the coupling case of NO than previously available, because we can measure and simulate the high-resolution and broadband mid-IR Zeeman spectrum for both low and high rotational levels of the two subsystems. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Optics ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Optics ; Physics |
| 关键词[WOS] | FARADAY MODULATION SPECTROSCOPY ; MAGNETIC-FIELDS ; ROTATION SPECTROSCOPY ; SENSITIVE DETECTION ; ELECTRONIC-SPECTRA ; STERN-GERLACH ; NO ; RADICALS ; MOLECULE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000393901400001 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/10032]  |
| 专题 | 武汉物理与数学研究所_高技术创新与发展中心 |
| 作者单位 | Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Natl Lab Optoelect, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Kuijun,Liu, Linmei,Chen, Zhenwei,et al. High-resolution and broadband mid-infrared Zeeman spectrum of gas-phase nitric oxide using a quantum cascade laser around 5.2 mu m[J]. JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS,2017,50(3). |
| APA | Wu, Kuijun,Liu, Linmei,Chen, Zhenwei,Cheng, Xuewu,Yang, Yong,&Li, Faquan.(2017).High-resolution and broadband mid-infrared Zeeman spectrum of gas-phase nitric oxide using a quantum cascade laser around 5.2 mu m.JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS,50(3). |
| MLA | Wu, Kuijun,et al."High-resolution and broadband mid-infrared Zeeman spectrum of gas-phase nitric oxide using a quantum cascade laser around 5.2 mu m".JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS 50.3(2017). |
入库方式： OAI收割
来源：武汉物理与数学研究所
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