Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores
文献类型：期刊论文
| 作者 | Huang, Jiang-Bo1; Bai, Xing-Feng1; Li, Li1; Zheng, Zhan-Jiang1; Xu, Zheng1; Cui, Yu-Ming1; Cao, Jian1; Xu LW(徐利文)1,2 |
| 刊名 | Chemistry - A European Journal
 |
| 出版日期 | 2017 |
| 卷号 | 23期号:17页码:4055-4059 |
| 关键词 | aggregation-induced emission lithium molecular recognition selective oxidation terpyridine |
| ISSN号 | 0947-6539 |
| 通讯作者 | Xu, Zheng ; 徐利文 |
| 英文摘要 | Direct functionalization of terpyridines is an increasingly important topic in the field of dyes and catalysis as well as supramolecular chemistry, but its synthesis and transformation is usually challenging. Herein, a HOMO-raising strategy is reported for the construction of a super-stable novel terpyridine chromophores, in which the selective oxidation of terpyridines at its 3-position was determined successfully to the synthesis of phenol-functionalization of terpyridines (TPyOHs) bearing a hydrogen bonding group. The corresponding TPyOHs displayed strong aggregation-induced emission and exhibited highly selective and visual detection of ZnII cation with a record green terpyridine-based luminophore with nanomolar sensitivity (125 nm). |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Founder of China (No. 21472031;21503060); Zhejiang Provincial Natural Science Foundation of China (LY17E030003;LY17B030005); Science and Technology Department of Zhejiang Province (2015C31138);Hangzhou Science and Technology Bureau of China (20170533B08;20160432B08) |
| 语种 | 英语 |
| WOS记录号 | WOS:000399312700006 |
| 源URL | [http://210.77.64.217/handle/362003/21779]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Jiang-Bo,Bai, Xing-Feng,Li, Li,et al. Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores[J]. Chemistry - A European Journal,2017,23(17):4055-4059. |
| APA | Huang, Jiang-Bo.,Bai, Xing-Feng.,Li, Li.,Zheng, Zhan-Jiang.,Xu, Zheng.,...&Xu LW.(2017).Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores.Chemistry - A European Journal,23(17),4055-4059. |
| MLA | Huang, Jiang-Bo,et al."Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores".Chemistry - A European Journal 23.17(2017):4055-4059. |
入库方式： OAI收割
来源：兰州化学物理研究所
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