K3MB5O10 (M = Zn and Cd) with d(10) configuration: Efficient and reusable catalysts for dehalogenation of halophenols
文献类型：期刊论文
| 作者 | Fan, XY (Fan, Xiaoyun); Lau, J (Lau, Jing); Lai, KR (Lai, Kangrong); Wang, CY (Wang, Chuanyi) |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2017 |
| 卷号 | 206期号:5页码:599-607 |
| 关键词 | D-10 configuration Borate Internal electric field Dehalogenation |
| 通讯作者 | Fan, XY ; Wang, CY |
| 英文摘要 | Two isostructural d(10) configuration non-centrosymmetric materials: K3ZnB5O10 (KZBO) and K3CdB5O10 (KCBO) can act as efficient and reusable catalysts in the dehalogenation of halophenols. More than 90% of the 2, 4-DXP were degraded within 10 min with the dehalogenation efficiency 2, 4-DBP > 2, 4-DCP > 2, 4-DFP, the dehalogenation efficiency is almost 10 times higher than that of commercial P25 TiO2 catalyst in the present reaction conditions. The internal electric field due to the distorted [MO4] tetrahedral and [BO3] units promote the charge separation in the initial process of photoexcitation and d(10) configuration of Zn and Cd with large dispersion is useful for photoexcited electron transfers without recombination, thus enhance the photocatalytic activity. The dehalogenation pathways with KCBO outlined both oxidative and reductive dehalogenation. Our work is expected to offer new insight into photocatalytic theory for better understandings to photocatalytic reactions and rational design and synthesis of photocatalysts with high activity. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000395602000060 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4761]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Urumqi 830011, Peoples R China 2.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China 3.Changji Univ, Dept Phys, Changji 831100, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, XY ,Lau, J ,Lai, KR ,et al. K3MB5O10 (M = Zn and Cd) with d(10) configuration: Efficient and reusable catalysts for dehalogenation of halophenols[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2017,206(5):599-607. |
| APA | Fan, XY ,Lau, J ,Lai, KR ,&Wang, CY .(2017).K3MB5O10 (M = Zn and Cd) with d(10) configuration: Efficient and reusable catalysts for dehalogenation of halophenols.APPLIED CATALYSIS B-ENVIRONMENTAL,206(5),599-607. |
| MLA | Fan, XY ,et al."K3MB5O10 (M = Zn and Cd) with d(10) configuration: Efficient and reusable catalysts for dehalogenation of halophenols".APPLIED CATALYSIS B-ENVIRONMENTAL 206.5(2017):599-607. |
入库方式： OAI收割
来源：新疆理化技术研究所
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