A(3)Sr(2)P(7)O(21) (A = Rb, Cs): Two Polyphosphates Based on Different Types of P-O Chains and Ring Structures
文献类型：期刊论文
| 作者 | Abudoureheman, M (Abudoureheman, Maierhaba); Han, SJ (Han, Shujuan) ; Wang, Y (Wang, Ying); Lei, BH (Lei, Bing-Hua); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
|
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2017 |
| 卷号 | 56期号:7页码:3939-3945 |
| 通讯作者 | Han, SJ ; Pan, SL |
| 英文摘要 | Two polyphosphates containing two types of polymerization of the [PO4] groups, Rb3Sr2P7O22 and Cs3Sr2P7O21; were grown through a spontaneous nucleation method. Single-crystal X-ray diffraction data Were collected in order to determine their structures. Interestingly, Rb3Sr2P7O21 is the first example of two kinds of [PO3](infinity) linear Chains coexisting in one phosphate structure. However, in the structure of Cs3Sr2P7O22, the isolated [P4O12] ring and the 1D [PO3](infinity) chain can be obsetved, which is also rare in phosphates. After careful structural analysis, the alkali-metal cations have an effect on the polymerization of the [PO4] groups and make Rb3Sr2P7O21 and Cs3Sr2P7O21 crystallize in different space groups: What is more, IR spectra, UV-vis-NIR diffuse reflectance spectroscopy data, and first-principles theoretical calculations were adopted to determine the optical properties and the structure properties relationship of the compounds. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000398426000022 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4769]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Abudoureheman, M ,Han, SJ ,Wang, Y ,et al. A(3)Sr(2)P(7)O(21) (A = Rb, Cs): Two Polyphosphates Based on Different Types of P-O Chains and Ring Structures[J]. INORGANIC CHEMISTRY,2017,56(7):3939-3945. |
| APA | Abudoureheman, M ,Han, SJ ,Wang, Y ,Lei, BH ,Yang, ZH ,&Pan, SL .(2017).A(3)Sr(2)P(7)O(21) (A = Rb, Cs): Two Polyphosphates Based on Different Types of P-O Chains and Ring Structures.INORGANIC CHEMISTRY,56(7),3939-3945. |
| MLA | Abudoureheman, M ,et al."A(3)Sr(2)P(7)O(21) (A = Rb, Cs): Two Polyphosphates Based on Different Types of P-O Chains and Ring Structures".INORGANIC CHEMISTRY 56.7(2017):3939-3945. |
入库方式： OAI收割
来源：新疆理化技术研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。