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Fluorooxoborates: Beryllium-Free Deep-Ultraviolet Nonlinear Optical Materials without Layered Growth
文献类型：期刊论文
| 作者 | Zhang, BB (Zhang, Bingbing); Shi, GQ (Shi, Guoqiang); Yang, ZH (Yang, Zhihua) ; Zhang, FF (Zhang, Fangfang); Pan, SL (Pan, Shilie)
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| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017 |
| 卷号 | 56期号:14页码:3916-3919 |
| 关键词 | boron deep-ultraviolet fluorooxoborates nonlinear optical materials second harmonic generation |
| 通讯作者 | Yang, ZH ; Pan, SL |
| 英文摘要 | Deep-ultraviolet nonlinear optical (DUV NLO) crystals are the key materials to extend the output range of solid-state lasers to below 200 nm. The only practical material KBe2BO3F2 suffers high toxicity through beryllium and strong layered growth. Herein, we propose a beryllium-free material design and synthesis strategy for DUV NLO materials. Introducing the (BO3F)(4-),(BO2F2)(3-), and (BOF3)(2-) groups in borates could break through the fixed 3DB-O network that would produce a larger birefringence without layering and simultaneously keep a short cutoff edge down to DUV. The theoretical and experimental studies on a series of fluorooxoborates confirm this strategy. Li2B6O9F2 is identified as aDUV NLO material with a large second harmonic generation efficiency (0.9 x KDP) and a large predicted birefringence (0.07) without layering. This study provides a feasible way to break down the DUV wall for NLO materials. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000397346200024 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4776]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | 1.Chinese Acad Sci, Dev Special Environm, Key Lab Funct Mat, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Dev, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, BB ,Shi, GQ ,Yang, ZH ,et al. Fluorooxoborates: Beryllium-Free Deep-Ultraviolet Nonlinear Optical Materials without Layered Growth[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(14):3916-3919. |
| APA | Zhang, BB ,Shi, GQ ,Yang, ZH ,Zhang, FF ,&Pan, SL .(2017).Fluorooxoborates: Beryllium-Free Deep-Ultraviolet Nonlinear Optical Materials without Layered Growth.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(14),3916-3919. |
| MLA | Zhang, BB ,et al."Fluorooxoborates: Beryllium-Free Deep-Ultraviolet Nonlinear Optical Materials without Layered Growth".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.14(2017):3916-3919. |
入库方式： OAI收割
来源：新疆理化技术研究所
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