Investigations on valence-change behaviors of europium ions in Eu-doped aluminate and silicate phosphors
文献类型:期刊论文
作者 | Peng MY(彭明营) ; Da Ning ; Qiao YB(乔延波) ; Wu Baotao ; Wang C(汪晨) ; Chen DP(陈丹平) ; Qiu JR(邱建荣) |
刊名 | j. rare earths
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出版日期 | 2006 |
卷号 | 24期号:6页码:749 |
关键词 | aluminate phosphors silicate phosphors Eu3+ Eu2+ rare earths |
ISSN号 | 1002-0721 |
中文摘要 | compounds of sr3al2o6: eu, sr4al14o25: eu, and baznsio4: eu were synthesized by high-temperature solid state reactions. the doping eu3+ ions were partially reduced to eu2+ in sr4al14o25: eu and baznsio4: eu prepared in an oxidizing atmosphere, n-2 + o-2. however, such an abnormal reduction process could not be performed in sr3al2o6: eu, which was also prepared in an atmosphere of n-2 + o-2. moreover, even though sr3al2o6: eu was synthesized in a reducing condition co, only part of the eu3+ ions was reduced to eu2+. the existence of trivalent and divalent europium ions was confirmed by photoluminescent spectra. the different valence-change behaviors of europium ions in the hosts were attributed to the difference in host crystal structures. the higher the crystal structure stiffness, the easier the reduction process from eu3+ to eu2+. |
收录类别 | EI |
语种 | 英语 |
WOS记录号 | WOS:000243319700022 |
公开日期 | 2009-09-24 |
源URL | [http://ir.siom.ac.cn/handle/181231/5215] ![]() |
专题 | 上海光学精密机械研究所_高功率激光单元技术研发中心 |
推荐引用方式 GB/T 7714 | Peng MY,Da Ning,Qiao YB,et al. Investigations on valence-change behaviors of europium ions in Eu-doped aluminate and silicate phosphors[J]. j. rare earths,2006,24(6):749, 753. |
APA | 彭明营.,Da Ning.,乔延波.,Wu Baotao.,汪晨.,...&邱建荣.(2006).Investigations on valence-change behaviors of europium ions in Eu-doped aluminate and silicate phosphors.j. rare earths,24(6),749. |
MLA | 彭明营,et al."Investigations on valence-change behaviors of europium ions in Eu-doped aluminate and silicate phosphors".j. rare earths 24.6(2006):749. |
入库方式: OAI收割
来源:上海光学精密机械研究所
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