Rotamers of m-aminophenol cation studied by mass analyzed threshold ionization spectroscopy and theoretical calculations
文献类型：期刊论文
| 作者 | Xie, Y; Su, HW; Tzeng, WB |
| 刊名 | chemical physics letters
 |
| 出版日期 | 2004-08-11 |
| 卷号 | 394期号:1-3页码:182-187 |
| 产权排序 | 2;1 |
| 英文摘要 | the vibrationally resolved spectra of selected rotamers of m-aminophenol have been recorded by mass analyzed threshold ionization spectroscopy in connection with two-color resonant two-photon excitation scheme. the adiabatic ionization energies of the cis and trans rotamers are 61460 +/- 5 and 61734 +/- 5 cm(-1), respectively. the frequencies of modes 1 (breathing) and 18a (in-plane ch bending) are measured to be 744 and 1097 cm(-1) for the cis, and 736 and 1104 cm(-1) for the trans rotamer, respectively. this indicates that different orientation of the oh with respect to the nh2 substituent only slightly influences these two modes. (c) 2004 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | polarized raman ; supersonic jet ; ir-spectra ; phenol ; vibrations ; rotation ; barrier ; crystal ; isomers ; ion |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000223241800035 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/81187]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 106, Taiwan 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie, Y,Su, HW,Tzeng, WB. Rotamers of m-aminophenol cation studied by mass analyzed threshold ionization spectroscopy and theoretical calculations[J]. chemical physics letters,2004,394(1-3):182-187. |
| APA | Xie, Y,Su, HW,&Tzeng, WB.(2004).Rotamers of m-aminophenol cation studied by mass analyzed threshold ionization spectroscopy and theoretical calculations.chemical physics letters,394(1-3),182-187. |
| MLA | Xie, Y,et al."Rotamers of m-aminophenol cation studied by mass analyzed threshold ionization spectroscopy and theoretical calculations".chemical physics letters 394.1-3(2004):182-187. |
入库方式： OAI收割
来源：大连化学物理研究所
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