The reaction route and active site of catalytic decomposition of hydrazine over molybdenum nitride catalyst
文献类型：期刊论文
| 作者 | Chen, XW; Zhang, T; Zheng, MY; Wu, ZL; Wu, WC; Li, C |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2004-06-10 |
| 卷号 | 224期号:2页码:473-478 |
| 关键词 | molybdenum nitride hydrazine decomposition Fr-IR spectroscopy hydrazine adsorption |
| 产权排序 | 1;1 |
| 英文摘要 | the catalytic properties of the passivated, reduced passivated, and fresh bulk molybdenum nitride for hydrazine decomposition were evaluated in a microreactor. the reaction route of hydrazine decomposition over molybdenum nitride catalysts seems to be the same as that of ir/gamma-al2o3 catalysts. below 673 k, the hydrazine decomposes into n-2 and nh3. above 673 k, the hydrazine decomposes into n-2 and nh3 first, and then the produced nh3 further dissociates into n-2 and h-2. from the in situ ft-ir spectroscopy, hydrazine is adsorbed and decomposes mainly on the mo site of the mo2n/gamma-al2o3 catalyst. (c) 2004 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | ir/al2o3 catalysts ; carbide ; iridium ; spectroscopy ; adsorption ; tungsten ; alumina ; oxygen |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000221601100025 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/81189]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, XW,Zhang, T,Zheng, MY,et al. The reaction route and active site of catalytic decomposition of hydrazine over molybdenum nitride catalyst[J]. journal of catalysis,2004,224(2):473-478. |
| APA | Chen, XW,Zhang, T,Zheng, MY,Wu, ZL,Wu, WC,&Li, C.(2004).The reaction route and active site of catalytic decomposition of hydrazine over molybdenum nitride catalyst.journal of catalysis,224(2),473-478. |
| MLA | Chen, XW,et al."The reaction route and active site of catalytic decomposition of hydrazine over molybdenum nitride catalyst".journal of catalysis 224.2(2004):473-478. |
入库方式： OAI收割
来源：大连化学物理研究所
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