Trichloroisocyanuric acid: A convenient oxidation reagent for phase-transfer catalytic epoxidation of enones under non-aqueous conditions
文献类型：期刊论文
| 作者 | Ye, JX; Wang, YC; Chen, JP; Liang, XM |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2004-05-01 |
| 卷号 | 346期号:6页码:691-696 |
| 关键词 | enones epoxidation organic catalysis phase-tranfer catalysis trichloroisocyanuric acid |
| 产权排序 | 1;1 |
| 英文摘要 | trichloroisocyanuric acid (tcca) is a cheap, safe and readily available alternative to the commonly used hydrogen peroxide and hypochlorite for the phase-transfer catalytic epoxidation of alpha,beta-enones under non-aqueous conditions. a variety of chalcone derivatives give the corresponding epoxides with quantitative conversion and satisfactory yields in just a few hours under mild conditions. an asymmetric variant of the epoxidation can be carried out in the presence of chiral n-anthracenylmethylcinchonidine bromide catalyst giving 73-93% ees and 76-94% yields. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | transfer mediated epoxidation ; weitz-scheffer epoxidation ; alpha-amino-acids ; asymmetric epoxidation ; alpha,beta-unsaturated ketones ; mild conditions ; stereoselective epoxidation ; heterogeneous system ; cinchona alkaloids ; polyamino acid |
| 收录类别 | SCI ; CCR |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000222129300016 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/81221]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ye, JX,Wang, YC,Chen, JP,et al. Trichloroisocyanuric acid: A convenient oxidation reagent for phase-transfer catalytic epoxidation of enones under non-aqueous conditions[J]. advanced synthesis & catalysis,2004,346(6):691-696. |
| APA | Ye, JX,Wang, YC,Chen, JP,&Liang, XM.(2004).Trichloroisocyanuric acid: A convenient oxidation reagent for phase-transfer catalytic epoxidation of enones under non-aqueous conditions.advanced synthesis & catalysis,346(6),691-696. |
| MLA | Ye, JX,et al."Trichloroisocyanuric acid: A convenient oxidation reagent for phase-transfer catalytic epoxidation of enones under non-aqueous conditions".advanced synthesis & catalysis 346.6(2004):691-696. |
入库方式： OAI收割
来源：大连化学物理研究所
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