Heat capacities and thermodynamic properties of chrysanthemic acid
文献类型：期刊论文
| 作者 | Xue, B; Wang, JY; Tan, ZC; Lu, SW; Meng, SH |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2004 |
| 卷号 | 76期号:3页码:965-973 |
| 关键词 | adiabatic calorimetry chrysanthemic acid heat capacity TG thermal decomposition thermodynamic function |
| 产权排序 | 2;3 |
| 英文摘要 | the heat capacities of chrysanthemic acid in the temperature range from 80 to 400 k were measured with a precise automatic adiabatic calorimeter. the chrysanthemic acid sample was prepared with the purity of 0.9855 mole fraction. a solid-liquid fusion phase transition was observed in the experimental temperature range. the melting point, t-m, enthalpy and entropy of fusion, delta(fus)h(m), delta(fus)s(m), were determined to be 390.741 +/- 0.002 k, 14.51 +/- 0.13 kj mol(-1), 37.13 +/- 0.34 j mol(-1) k-1, respectively. the thermodynamic functions of chrysanthemic acid, h-(t)-h-(298.15), s-(t)-s-(298.15) and g((t))-g((298.15)) were reported with a temperature interval of 5 k. the tg analysis under the heating rate of 10 k min(-1) confirmed that the thermal decomposition of the sample starts at ca. 410 k and terminates at ca. 471 k. the maximum decomposition rate was obtained at 466 k. the purity of the sample was determined by a fractional melting method. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | adiabatic calorimeter ; alpha-alumina ; standard |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000222091300028 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/81459]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Shenyang Univ Technol, Sch Petrochem Engn, Liaoyang, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, B,Wang, JY,Tan, ZC,et al. Heat capacities and thermodynamic properties of chrysanthemic acid[J]. journal of thermal analysis and calorimetry,2004,76(3):965-973. |
| APA | Xue, B,Wang, JY,Tan, ZC,Lu, SW,&Meng, SH.(2004).Heat capacities and thermodynamic properties of chrysanthemic acid.journal of thermal analysis and calorimetry,76(3),965-973. |
| MLA | Xue, B,et al."Heat capacities and thermodynamic properties of chrysanthemic acid".journal of thermal analysis and calorimetry 76.3(2004):965-973. |
入库方式： OAI收割
来源：大连化学物理研究所
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